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Journal of Materials Science

Erschienen in:

29.03.2021 | Chemical routes to materials

Superhydrophobic reduced graphene oxide@poly(lactic acid) foam with electrothermal effect for fast separation of viscous crude oil

verfasst von: Qingtao Zeng, Piming Ma, Dehui Lai, Xuejun Lai, Xingrong Zeng, Hongqiang Li

Erschienen in: Journal of Materials Science | Ausgabe 19/2021

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Abstract

In recent years, eco-friendly superhydrophobic materials have aroused much attention. Herein, biodegradable poly(lactic acid) (PLA) was selected as basic material to fabricate superhydrophobic foam with electrothermal effect by dip-coating graphene oxide (GO) on the surface of PLA foam constructed through freeze-drying process and the subsequent reduction with hydroiodic acid. Owing to the micro-nano rough structure of pristine PLA foam and the coverage of low-surface-energy reduced GO (rGO), the obtained rGO@PLA foam exhibited excellent water repellency with a high water contact angle of 150.6°. The foam was able to separate different oil–water mixtures, and the separation efficiencies were all above 96%. Importantly, the rGO layer also endowed the PLA foam with electrothermal conversion capability, and the surface temperature of the rGO@PLA foam rapidly increased to 129.5 °C from 30.8 °C at a low voltage of 15 V within only 120 s. By means of the generated Joule heat, the rGO@PLA foam was successfully applied for separating viscous crude oil from water, and the separation rate was about 14 times higher than that without voltage. Our findings conceivably stand out as a new tool to fabricate functional biodegradable materials for clean-up of viscous crude oil.

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Vorheriger Artikel Synthesis of mesoporous carbon nitride by molten salt-assisted silica aerogel for Rhodamine B adsorption and photocatalytic degradation

Nächster Artikel Experimental and numerical investigation of key microstructural features influencing the localization of plastic deformation in Fe-TiB2 metal matrix composite

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Tian G, Zhang M, Yan H, Zhang J, Sun Q, Guo R (2020) Nonfluorinated, mechanically stable, and durable superhydrophobic 3D foam iron for high efficient oil/water continuous separation. Appl Surf Sci 527:146861. https://doi.org/10.1016/j.apsusc.2020.146861CrossRef

Yu Y, Shi X, Liu L, Yao J (2021) Highly compressible and durable superhydrophobic cellulose aerogels for oil/water emulsion separation with high flux. J Mater Sci 56:2763–2776. https://doi.org/10.1007/s10853-020-05441-5CrossRef

Liu Y, Wang X, Feng S (2019) Nonflammable and magnetic sponge decorated with polydimethylsiloxane brush for multitasking and highly efficient oil-water separation. Adv Funct Mater 29:1902488. https://doi.org/10.1002/adfm.201902488CrossRef

Yu C, Jiang J, Liu Y, Liu K, Situ Z, Tian L, Luo W, Hong P, Li Y (2021) Facile fabrication of compressible, magnetic and superhydrophobic poly(DVB-MMA) sponge for high-efficiency oil-water separation. J Mater Sci 56:3111–3126. https://doi.org/10.1007/s10853-020-05471-zCrossRef

Su X, Li H, Lai X, Zhang L, Wang J, Liao X, Zeng X (2017) Vapor-liquid sol-gel approach to fabricating highly durable and robust superhydrophobic polydimethylsiloxane@silica surface on polyester textile for oil-water separation. ACS Appl Mater Interfaces 9:28089–28099CrossRef

Chen L, Wu S, Lu H, Huang K, Zhao L (2015) Numerical simulation and structural optimization of the inclined oil/water separator. PLoS ONE 10:e0124095. https://doi.org/10.1371/journal.pone.0124095CrossRef

Liang H, Guan Q, Chen L, Zhu Z, Zhang W, Yu S (2012) Macroscopic-scale template synthesis of robust carbonaceous nanofiber hydrogels and aerogels and their applications. Angew Chem Int Ed 51:5101–5105CrossRef

Kujawinski E, Soule M, Valentine D, Boysen A, Longnecker K, Redmond M (2011) Fate of dispersants associated with the deepwater horizon oil spill. Environ Sci Technol 45:1298–1306CrossRef

Bai W, Lin H, Chen K, Xu J, Chen J, Zhang X, Zeng R, Lin J, Xu Y (2020) Eco-friendly stable cardanol-based benzoxazine modified superhydrophobic cotton fabrics for oil–water separation. Sep Purif Technol 253:117545. https://doi.org/10.1016/j.seppur.2020.117545CrossRef

10.

Wang S, Zhu Y, Xia F, Xi J, Wang N, Feng L, Jiang L (2006) The preparation of a superhydrophilic carbon film from a superhydrophobic lotus leaf. Carbon 44:1848–1850CrossRef

11.

Liu K, Du J, Wu J, Jiang L (2012) Superhydrophobic gecko feet with high adhesive forces towards water and their bio-inspired materials. Nanoscale 4:768–772CrossRef

12.

Bai F, Wu J, Gong G, Guo L (2014) Biomimetic “water strider leg” with highly refined nanogroove structure and remarkable water-repellent performance. ACS Appl Mater Interfaces 6:16237–16242CrossRef

13.

Yang M, Jiang C, Liu W, Liang L, Xie Y, Shi H, Zhang F, Pi K (2020) A water-rich system of constructing durable and fluorine-free superhydrophobic surfaces for oil/water separation. Appl Surf Sci 507:145165. https://doi.org/10.1016/j.apsusc.2019.145165CrossRef

14.

Nine J, Tung T, Alotaibi F, Tran D, Losic D (2017) Facile adhesion-tuning of superhydrophobic surfaces between “lotus” and “petal” effect and their influence on icing and deicing properties. ACS Appl Mater Interfaces 9:8392–8402

15.

Yun S, Luo H, Gao Y (2014) Ambient-pressure drying synthesis of large resorcinol-formaldehyde-reinforced silica aerogels with enhanced mechanical strength and superhydrophobicity. J Mater Chem A 2:14542–14549CrossRef

16.

Zhang L, Li H, Lai X, Su X, Liang T, Zeng X (2017) Thiolated graphene-based superhydrophobic sponges for oil-water separation. Chem Eng J 316:736–743CrossRef

17.

Jiang C, Liu W, Yang M, Zhang F, Shi H, Xie Y, Wang Z (2019) Robust fabrication of superhydrophobic and photocatalytic self-cleaning cotton textiles for oil-water separation via thiol-ene click reaction. J Mater Sci 54:7369–7382. https://doi.org/10.1007/s10853-019-03373-3CrossRef

18.

Zhang L, Xu L, Sun Y, Yang N (2016) Robust and durable superhydrophobic polyurethane sponge for oil/water separation. Ind Eng Chem Res 55:11260–11268CrossRef

19.

Anupriyanka T, Shanmugavelayutham G, Sarma B, Mariammal M (2020) A single step approach of fabricating superhydrophobic PET fabric by using low pressure plasma for oil-water separation. Coll Surf A Physicochem Eng Asp 600:124949. https://doi.org/10.1016/j.colsurfa.2020.124949CrossRef

20.

Ge J, Shi L, Wang Y, Zhao H, Yao H, Zhu Y, Zhu H, Wu H, Yu S (2017) Joule-heated graphene-wrapped sponge enables fast clean-up of viscous crude-oil spill. Nat Nanotechnol 12:434–441CrossRef

21.

Wang Y, Zhou L, Luo X, Zhang Y, Sun J, Ning X, Yuan Y (2019) Solar-heated graphene sponge for high-efficiency clean-up of viscous crude oil spill. J Clean Prod 230:995–1002CrossRef

22.

Shi J, Zhang L, Xiao P, Huang Y, Chen P, Wang X, Gu J, Zhang J, Chen T (2018) Biodegradable PLA nonwoven fabric with controllable wettability for efficient water purification and photocatalysis degradation. ACS Sustain Chem Eng 6:2445–2452CrossRef

23.

Wu B, Zeng Q, Niu D, Yang W, Dong W, Chen M, Ma P (2019) Design of supertoughened and heat-resistant PLLA/elastomer blends by controlling the distribution of stereocomplex crystallites and the morphology. Macromolecules 52:1092–1103CrossRef

24.

Jing M, Che J, Xu S, Liu Z, Fu Q (2018) The effect of surface modification of glass fiber on the performance of poly(lactic acid) composites: graphene oxide versus silane coupling agents. Appl Surf Sci 435:1046–1056CrossRef

25.

Liu Y, Wang Y, Zhang M, Qi Z, Zeng J, Tian N, Li Q (2021) A new insight into formation of 3D porous biomaterials. J Mater Sci 56:3404–3413. https://doi.org/10.1007/s10853-020-05447-zCrossRef

26.

Gu J, Xiao P, Chen P, Zhang L, Wang H, Dai L, Song L, Huang Y, Zhang J, Chen T (2017) Functionalization of biodegradable PLA nonwoven fabric as superoleophilic and superhydrophobic material for efficient oil absorption and oil/water separation. ACS Appl Mater Interfaces 9:5968–5973CrossRef

27.

Wang Y, Yang H, Chen Z, Chen N, Pang X, Zhang L, Minari T, Liu X, Liu H, Chen J (2018) Recyclable oil-absorption foams via secondary phase separation. ACS Sustain Chem Eng 6:13834–13843CrossRef

28.

Wang X, Pan Y, Liu X, Liu H, Li N, Liu C, Schubert D, Shen C (2019) Facile fabrication of superhydrophobic and eco-friendly poly(lactic acid) foam for oil-water separation via skin seeling. ACS Appl Mater Interfaces 11:14362–14367CrossRef

29.

Wu J, Li H, Lai X, Chen Z, Zeng X (2020) Conductive and superhydrophobic F-rGO@CNTs/chitosan aerogel for piezoresistive pressure sensor. Chem Eng J 386:123998. https://doi.org/10.1016/j.cej.2019.123998CrossRef

30.

Ma P, Lv P, Xu P, Du M, Zhu H, Dong W, Chen M (2018) Design of bio-based conductive and fast crystallizing nanocomposites with controllable distribution of multiwalled carbon nanotubes via interfacial stereocomplexation. Chem Eng J 336:223–232CrossRef

31.

Xie Q, Han L, Shan G, Bao Y, Pan P (2016) Polymorphic crystalline structure and crystal morphology of enantiomeric poly(lactic acid) blends tailored by a self-assemblable aryl amide nucleator. ACS Sustain Chem Eng 4:2680–2688CrossRef

32.

Liu Y, Ma J, Wu T, Wang X, Huang G, Liu Y, Qiu H, Li Y, Wang W, Guo J (2013) Cost-effective reduced graphene oxide-coated polyurethane sponge as a highly efficient and reusable oil-absorbent. ACS Appl Mater Interfaces 5:10018–10026CrossRef

33.

Cheng Y, Barras A, Lu S, Xu W, Szunerits S, Boukherroub R (2020) Fabrication of oxide/polydopamine/PFDT membrane for efficient oil/water separation. Sep Purif Technol 236:116240. https://doi.org/10.1016/j.seppur.2019.116240CrossRef

34.

Tan Q, Wang C, Cao Y, Liu X, Cao H, Wu G, Xu B (2020) Synthesis of a zinc ferrite effectively encapsulated by reduced graphene oxide composite anode material for high-rate lithium ion storage. J Coll Interface Sci 579:723–732CrossRef

35.

Fan X, Cai C, Gao J, Han X, Li J (2020) Hydrothermal reduced graphene oxide membranes for dyes removing. Sep Purif Technol 241:116730. https://doi.org/10.1016/j.seppur.2020.116730CrossRef

36.

Zhu H, Chen D, An W, Li N, Xu Q, Li H, He J, Lu J (2015) A robust and cost-effective superhydrophobic graphene foam for efficient oil and organic solvent recovery. Small 11:5222–5229CrossRef

37.

Zhou C, Chen Z, Yang H, Hou K, Zeng X, Zheng Y, Cheng J (2017) Nature-inspired strategy toward superhydrophobic fabrics for versatile oil/water separation. ACS Appl Mater Interfaces 9:9184–9194CrossRef

38.

Liang H, Guan Q, Chen L, Zhu Z, Zhang W, Yu S (2011) Macroscopic-scale template synthesis of robust carbonaceous nanofiber hydrogels and aerogels and their applications. Angew. Chem Int Ed 51:5101–5105CrossRef

39.

Chao H, Ze Li, Wang Y, Gao J, Dai K, Zheng G, Liu C, Shen C, Song H, Guo Z (2017) Comparative assessment of the strain-sensing behaviors of polylactic acid nanocomposites: reduced graphene oxide or carbon nanotubes. J Mater Chem C 5:2318–2328CrossRef

40.

Liu W, Jiang H, Ru Y, Zhang X, Qiao J (2018) Conductive graphene-melamine sponge prepared via microwave irradiation. ACS Appl Mater Interfaces 10:24776–24783CrossRef

41.

Gourhari C, Pugazhenthi G, Vimal K (2019) Exfoliated graphene-dispersed poly (lactic acid)-based nanocomposite sensors for ethanol detection. Polym Bull 76:2367–2386CrossRef

42.

Luo F, Fan Y, Peng G, Xu S, Yang Y, Yuan K, Liu J, Ma W, Xu W, Zhu Z, Zhang X, Mishchenko A, Ye Y, Huang H, Han Z, Ren W, Novoselov K, Zhu M, Qin S (2019) Graphene thermal emitter with enhanced Joule heating and localized light emission in air. ACS Photonics 6:2117–2125CrossRef

Titel: Superhydrophobic reduced graphene oxide@poly(lactic acid) foam with electrothermal effect for fast separation of viscous crude oil
verfasst von: Qingtao Zeng
Piming Ma
Dehui Lai
Xuejun Lai
Xingrong Zeng
Hongqiang Li
Publikationsdatum: 29.03.2021
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 19/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-021-06029-3

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