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Metallurgical and Materials Transactions B
Erschienen in: Metallurgical and Materials Transactions B 6/2018

10.09.2018

The Binary Alkali Nitrate and Chloride Phase Diagrams: NaNO3-KNO3, LiNO3-NaNO3, LiNO3-KNO3, and NaCl-KCl

verfasst von: Mehedi Bin Mohammad, Peter Cadusch, Geoffrey Alan Brooks, M. Akbar Rhamdhani

Erschienen in: Metallurgical and Materials Transactions B | Ausgabe 6/2018

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Abstract

LiNO3-NaNO3, LiNO3-KNO3, NaNO3-KNO3, and NaCl-KCl phase relations were formulated using the regular solution model to obtain desired compositions for their potential application as a heat transfer fluid. The simultaneous nonlinear equations formed were solved numerically using a contour plot technique in Matlab. An algorithm was developed to determine the real roots of the coupled nonlinear equations and subsequent phase diagrams were constructed. The phase diagrams were compared with those predicted using FactSage thermochemical package and literature data from experimental studies. The calculated NaNO3-KNO3 phase diagram shows that this system has a eutectic point at 0.5 mole fraction of KNO3 with a eutectic temperature of 220.85 °C, while the LiNO3-KNO3 system was found to have a eutectic point at 0.44 mole fraction LiNO3 at 137 °C. The LiNO3-NaNO3 system shows a eutectic at 0.524 mole fraction LiNO3 at 192.8 °C, and finally the NaCl-KCl system has a eutectic point at 0.48 mole fraction NaCl at 634 °C. The liquidus and solidus curves obtained fitted close against values obtained from the quasi-chemical model used in FactSage and experimental values from the literature. This study showed that the regular solution model combined with the contour plots approach can sufficiently describe the liquidus–solidus curves of the alkali binary nitrate and chloride systems and could be a useful method for predicting the phase diagrams for higher order alkali nitrates and chlorides.
Vorheriger Artikel Preparation of Vanadium Nitride by Magnesiothermic Reduction of V2O3 in Nitrogen Atmosphere
Nächster Artikel Effects of Particle Diameter and Coke Layer Thickness on Solid Flow and Stress Distribution in BF by 3D Discrete Element Method

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Literatur
1.
R.W. Bradshaw, and C.E. Tyner: In 1988 Summer National Meeting, American Institute of Chemical Engineering (AIChE), Denver, Colorado, USA, 1988.
2.
F.S. Barnes, J.G. Levine: Large Energy Storage Systems Handbook. Taylor & Francis Group/CRC Press, Boca Raton, 2011
3.
H Okamoto and TB Massalski, Journal of phase equilibria, 1993, vol. 14, pp. 316-335.
4.
Ursula R Kattner, JOM, 1997, vol. 49, pp. 14-19.
5.
Mats Hillert, Calphad, 1980, vol. 4, pp. 1-12.
6.
K.-C. Chou, Y.A. Chang, Berichte der Bunsengesellschaft für physikalische Chemie, 1989, vol. 93, pp. 735-741.
7.
Y.A. Chang, S. Chen, F. Zhang, X. Yan, F. Xie, R. Schmid-Fetzer, W.A. Oates, Progr. Mater. Sci., 2004, vol. 49, pp. 313-345.
8.
James Sangster, Journal of phase equilibria, 2000, vol. 21, pp. 241-268.
9.
Arthur D Pelton, Armand Gabriel and James Sangster, Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1985, vol. 81, pp. 1167-1172.
10.
K. H. Jürgen Buschow, R.W. Cahn, M.C. Flemings, B. Ilschner, E.J. Kramer, S. Mahajan, Encyclopedia of Materials: Science and Technology, Elsevier, London, 2001.
11.
HG Wiedemann and G Bayer, Journal of Thermal Analysis and Calorimetry, 1985, vol. 30, pp. 1273-1281.
12.
J.C. Zhao: Methods for Phase Diagram Determination. Elsevier Science, London, 2011.
13.
H.L. Lukas, S. G Fries, B. Sundman: Computational Thermodynamics: The Calphad Method. Cambridge University Press. Cambridge, 2007.
14.
D. S. Coleman and P. D. A. Lacy, Materials Research Bulletin, 1967, vol. 2, pp. 935-938.
15.
A.P. Miodownik, N. Saunders, P. Nash, B. Sundman. Applications of Thermodynamics in the Synthesis and Processing of Materials. TMS, Warrendale, 1995.
16.
Bo Sundman, Bo Jansson and Jan-Olof Andersson, Calphad, 1985, vol. 9, pp. 153-190.
17.
H. L. Lukas, E. Th Henig and B. Zimmermann, Calphad, 1977, vol. 1, pp. 225-236.
18.
H. L. Lukas, J. Weiss and E. Th Henig, Calphad, 1982, vol. 6, pp. 229-251.
19.
Mats Hillert and Bo Sundman, Calphad, 2001, vol. 25, pp. 599-605.
20.
E.M. Levin, and H.F. McMurdie: Phase Diagrams for Ceramists, 1975 Supplement, American Ceramic Society, Columbus, OH, 1975.
21.
J.M. Prausnitz, R.N. Lichtenthaler, E.G. de Azevedo: Molecular Thermodynamics of Fluid-Phase Equilibria. Pearson Education, London, 1998.
22.
Jan V Sengers: Applied Thermodynamics of Fluids. Royal Society of Chemistry, 2010.
23.
Zahra Nickmand and Seyed Foad Aghamiri, Journal of Dispersion Science and Technology, 2010, vol. 31, pp. 1638-1647.
24.
Evelyne Neau, Joan Escandell and Christophe Nicolas, Industrial & Engineering Chemistry Research, 2010, vol. 49, pp. 7580-7588.
25.
WANG Yu, SHAO Guoquan, LI Shaobo, SUN Yimin and QIAO Zhiyu, Journal of Rare Earths, 2009, vol. 27, pp. 300-303.
26.
Grant M Wilson, Journal of the American Chemical Society, 1964, vol. 86, pp. 127-130.
27.
Koichiro Nakanishi, Industrial & Engineering Chemistry Fundamentals, 1970, vol. 9, pp. 449-453.
28.
Milton Blander and SJ Yosim, The Journal of Chemical Physics, 1963, vol. 39, pp. 2610-2616.
29.
ML Saboungi, H Schnyders, MS Foster and M Blander, The Journal of Physical Chemistry, 1974, vol. 78, pp. 1091-1096.
30.
D. R. Waldbaum, Geochimica et Cosmochimica Acta, 1969, vol. 33, pp. 1415-1427.
31.
P.D. Myers Jr., D.Y. Goswami, Applied Thermal Engineering, 2016, vol. 109, pp. 889-900.
32.
C. M. McDonald and C. A. Floudas, Computers & Chemical Engineering, 1995, vol. 19, pp. 1111-1139.
33.
J.M. Ortega, W.C. Rheinboldt: Iterative Solution of Nonlinear Equations in Several Variables. Academic Press, New York, 1970.
34.
M. J. Maeso and J. Largo, Thermochimica Acta, 1993, vol. 223, pp. 145-156.
35.
D. A. Nissen and B. H. Van Domelen, The Journal of Physical Chemistry, 1975, vol. 79, pp. 2003-2007.
36.
Leroy S. Hersh and O. J. Kleppa, The Journal of Chemical Physics, 1965, vol. 42, pp. 1309-1322.
37.
O. J. Kleppa, R. B. Clarke and L. S. Hersh, The Journal of Chemical Physics, 1961, vol. 35, pp. 175-180.
38.
O. J. Kleppa and L. S. Hersh, The Journal of Chemical Physics, 1961, vol. 34, pp. 351-358.
39.
O. J. Kleppa, The Journal of Physical Chemistry, 1960, vol. 64, pp. 1937-1940.
40.
C. M. Kramer and C. J. Wilson, Thermochimica Acta, 1980, vol. 42, pp. 253-264.
41.
Osami Abe, Taizo Utsunomiya and Yoshio Hoshino, Thermochimica Acta, 1984, vol. 78, pp. 251-260.
42.
Xuejun Zhang, Jun Tian, Kangcheng Xu and Yici Gao, Journal of Phase Equilibria, 2003, vol. 24, pp. 441-446.
43.
D Mantha, T Wang and RG Reddy, Journal of phase equilibria and diffusion, 2012, vol. 33, pp. 110-114.
44.
Kevin Coscia, Tucker Elliott, Satish Mohapatra, Alparslan Oztekin and Sudhakar Neti, Journal of Solar Energy Engineering, 2013, vol. 135, p. 021011.
45.
A.G. Bergman, S.I. Berul: Izv. Sekt., 1952, vol. 21, pp. 178–83.
46.
W.M. Madgin, H.V.A. Briscoe, R.S. Hughesdon, H.G. Smith, J. Read, S. Glasstone, S. Biggs, F.G. Pope, J. Chem. Soc. Trans., 1923, vol. 123, pp. 2914-2916.
47.
S.I. Berul, A.G. Bergman: Izv. Sekt, 1954, vol. 25, pp. 218-35.
48.
AN Kirgintsev and VI Kosyakov, Izv. Akad. Nauk. SSSR, Ser. Khim, 1968, vol. 10, pp. 2208-13.
49.
William Klement, Journal of Inorganic and Nuclear Chemistry, 1974, vol. 36, pp. 1916-1918.
50.
D.J. Rogers and G.J. Janz, J. Chem. Eng. Data, 1982, vol. 27, pp. 424–428.
51.
O. Greis, K. M. Bahamdan and B. M. Uwais, Thermochimica Acta, 1985, vol. 86, pp. 343-350.
52.
D. Sergeev, D. Kobertz and M. Müller, Thermochimica Acta, 2015, vol. 606, pp. 25-33.
53.
Markus Broström, Sonja Enestam, Rainer Backman and Kari Mäkelä, Fuel Processing Technology, 2013, vol. 105, pp. 142-148.
54.
ER Van Artsdalen and IS Yaffe, The Journal of Physical Chemistry, 1955, vol. 59, pp. 118-127.
55.
R. Benages-Vilau, T. Calvet, M.A. Cuevas-Diarte, H.A.J. Oonk, Phase Transit, 2015, 89, pp. 1-20.
56.
HAJ Oonk, Pure and Applied Chemistry, 2001, vol. 73, pp. 807-823.
57.
Fadi Awawdeh, Numerical Algorithms, 2010, vol. 54, pp. 395-409.
58.
Ebrahim Pourjafari and Hamed Mojallali, Swarm and Evolutionary Computation, 2012, vol. 4, pp. 33-43.
59.
C.R. Gwaltney, Y. Lin, L.D. Simoni, M.A. Stadtherr: Handbook of Granular Computing. Wiley, Chichester, 2008, pp. 81-96.
60.
R.T. Rockafellar: Convex Analysis. Princeton University Press, Princeton, 2015.
61.
S. Boyd, L. Vandenberghe: Convex Optimization. Cambridge University Press, Cambridge, 2004.
62.
H. Tuy: Convex Analysis and Global Optimization. Springer US, 1998.
63.
J.-B. Hiriart-Urruty, C. Lemaréchal: Convex Analysis and Minimization Algorithms I: Fundamentals. Springer Science & Business Media, New York, 2013.
64.
J. Borwein, A.S. Lewis: Convex Analysis and Nonlinear Optimization: Theory and Examples. Springer Science & Business Media, New York, 2010.
65.
I. Ekeland, R. Temam: Convex Analysis and Variational Problems. SIAM, Philadelphia, 1999.
66.
Y. Nesterov: Introductory Lectures on Convex Optimization: A Basic Course. Springer Science & Business Media, New York, 2013.
67.
I.K. Karpov, K.V. Chudnenko, D.A. Kulik, O.V. Avchenko, and V.A. Bychinskii: System, 2001, 3, 09.
68.
M.B. Mohammad, G. Brooks, M.A. Rhamdhani: in Applications of Process Engineering Principles Materials Processing, Energy and Environmental Technologies: An EPD Symposium in Honor of Professor Ramana G. Reddy. S. Wang, M.L. Free, A. Shafiq, Z. Mingming, and P.R. Taylor, Springer International Publishing, Cham, 2017, pp 531–39.
69.
70.
J. H. Hildebrand, The Journal of the American Chemical Society, 1929, vol. 51, pp. 66-80.
71.
Bo Sundman and John Ågren, Journal of Physics and Chemistry of Solids, 1981, vol. 42, pp. 297-301.
72.
J. H. Hildebrand, Journal of the American Chemical Society, 1916, vol. 38, pp. 1452-1473.
73.
J. Vidal: Thermodynamics: Applications in Chemical Engineering and the Petroleum Industry, Editions Technip, Paris, 2003.
74.
E.A. Guggenheim: Proceedings of the Royal Society of London. Series A - Mathematical and Physical Sciences, 1935, vol. 148, pp. 304–12.
75.
C Vallet, The Journal of Chemical Thermodynamics, 1972, vol. 4, pp. 105-114.
76.
S. Stølen, T. Grande: Chemical Thermodynamics of Materials: Macroscopic and Microscopic Aspects. Wiley, New York, 2004.
77.
R. DeHoff: Thermodynamics in Materials Science, 2nd edn. Taylor & Francis, New York, 2006.
78.
Vladimir Danek: Physico-chemical analysis of molten electrolytes. 1st ed. Elsevier Science, Amsterdam, Nehterlands, 2006.
79.
I. Prigogine and R. Defay: Chemical Thermodynamics. Longmans, Green 1954.
80.
W.D. Callister, D.G. Rethwisch: Fundamentals of Materials Science and Engineering: An Integrated Approach. Wiley, New York, 2012.
81.
CW Bale, P Chartrand, SA Degterov, G Eriksson, K Hack, R Ben Mahfoud, J Melançon, AD Pelton and S Petersen, Calphad, 2002, vol. 26, pp. 189-228.
82.
C. W. Bale, E. Bélisle, P. Chartrand, S. A. Decterov, G. Eriksson, A. E. Gheribi, K. Hack, I. H. Jung, Y. B. Kang, J. Melançon, A. D. Pelton, S. Petersen, C. Robelin, J. Sangster, P. Spencer and M. A. Van Ende, Calphad, 2016, vol. 54, pp. 35-53.
83.
Xuejun Zhang, Kangcheng Xu and Yici Gao, Thermochimica Acta, 2002, vol. 385, pp. 81-84.
84.
H. Ohtani, J. Mochinaga, K. Igarashi, Denki Journal, 1981, vol. 49, p. 19.
85.
CW Bale, E Bélisle, P Chartrand, SA Decterov, G Eriksson, K Hack, I-H Jung, Y-B Kang, J Melançon and AD Pelton, Calphad, 2009, vol. 33, pp. 295-311.
86.
K.E. Atkinson: An Introduction to Numerical Analysis. Wiley, New York, 2008.
87.
W.H. Press, S.A. Teukolsky, W.T. Vetterling, B.P. Flannery: Numerical Recipes in C. Cambridge University Press, Cambridge, 1996.
88.
É. Walter: Numerical Methods and Optimization. Springer, New York, 2014.
89.
J.E. Dennis Jr., R.B. Schnabel: Numerical Methods for Unconstrained Optimization and Nonlinear Equations. SIAM, Philadelphia, 1996.
90.
W.C. Rheinboldt: Methods for Solving Systems of Nonlinear Equations. SIAM, Philadelphia, 1998.
91.
Charles G Broyden, Mathematics of computation, 1965, vol. 19, pp. 577-593.
92.
J-F Tsai and M-H Lin, Engineering Optimization, 2007, vol. 39, pp. 649-659.
93.
J-B Hiriart-Urruty and M Torki, Applied Mathematics and Optimization, 2002, vol. 45, pp. 169-184.
94.
R.H. Hardaway: Proceedings of the December 9–11, 1968, Fall Joint Computer Conference, Part I, ACM. 1968. pp. 105–13.
95.
M.S. Petković, B. Neta, L.D. Petković, J. Džunić, Appl. Math. Comput., 2014, vol. 226, pp. 635-660.
96.
A.R. Conn, N.I.M. Gould, P.L. Toint: Trust Region Methods. SIAM, Philadelphia, 2000.
97.
W.H. Press: Numerical Recipes 3rd Edition: The Art of Scientific Computing. Cambridge University Press, Cambridge, 2007
98.
L.C.W. Dixon, G.P. Szegö: Towards Global Optimisation 2. North-Holland Pub. Co., Amsterdam, 1978.
99.
D.P. Bertsekas: Nonlinear programming. Athena Scientific, Belmont, 1999
100.
MATLAB User’s Guide, Inc., Natick, 1998, vol. 5, p. 333.
101.
J.H. Mathews, K.D. Fink: Numerical Methods using MATLAB. Prentice Hall, Upper Saddle River, 1999.
102.
W. Sun, Y.-X. Yuan: Optimization Theory and Methods: Nonlinear Programming. Springer Science & Business Media, New York, 2006.
103.
J.W. Harris, H. Stöcker: Handbook of Mathematics and Computational Science. Springer Science & Business Media, New York, 1998.
104.
Y Takahashi, R Sakamoto and M Kamimoto, International journal of thermophysics, 1988, vol. 9, pp. 1081-1090.
105.
P.D. Myers, D.Y. Goswami, E. Stefanakos: J. Solar Energy Eng., 2015, vol. 137, p. 041002.
106.
Q. Peng, X. Yang, X. Wei, J. Yang, and J. Ding, J. Lu: Proceedings of the Materials for Renewable Energy and Environment (ICMREE), 2013 International Conference on, IEEE, 2014, pp. 496–99.
107.
H.A.J. Oonk, M.T. Calvet: Equilibrium Between Phases of Matter: Phenomenology and Thermodynamics. Springer Science & Business Media, New York, 2007.
108.
R. D. Weir, T.W. de Loos: Measurement of the Thermodynamic Properties of Multiple Phases. Gulf Professional Publishing, Houston, 2005.
109.
Y Dessureault, J Sangster and AD Pelton, Journal de chimie physique, 1990, vol. 87, pp. 407-453.
110.
H.V.A. Briscoe, W.M. Madgin, J. Chem. Soc. Trans., 1923, vol. 123, pp. 1608-1618.
111.
Adelheid Kofler, Monatshefte für Chemie und verwandte Teile anderer Wissenschaften, 1955, vol. 86, pp. 643-652.
112.
DJ Hussink, Z. Phys. Chem, 1900, vol. 32, pp. 536-40.
113.
Kangcheng Xu, Journal of Physics and Chemistry of Solids, 1999, vol. 60, pp. 5-11.
114.
SG Ingle and SR Ghadekar, Journal of Physics D: Applied Physics, 1978, vol. 11, p. 913.
115.
M.B. Mohammad, G.A. Brooks, M.A. Rhamdhani, Metall. Mater. Trans. B, 2018, vol. 49, pp. 1482-1498.
116.
M.B. Mohammad, G.A. Brooks, M. A. Rhamdhani, Renewable Energy, 2016, 104, pp. 76-87.
Metadaten
Titel
The Binary Alkali Nitrate and Chloride Phase Diagrams: NaNO3-KNO3, LiNO3-NaNO3, LiNO3-KNO3, and NaCl-KCl
verfasst von
Mehedi Bin Mohammad
Peter Cadusch
Geoffrey Alan Brooks
M. Akbar Rhamdhani
Publikationsdatum
10.09.2018
Verlag
Springer US
Erschienen in
Metallurgical and Materials Transactions B / Ausgabe 6/2018
Print ISSN: 1073-5615
Elektronische ISSN: 1543-1916
DOI
https://doi.org/10.1007/s11663-018-1408-3

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