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Erschienen in: Journal of Materials Engineering and Performance 1/2023

20.06.2022 | Technical Article

The Corrosion Behavior of CoCrNi Medium Entropy Alloy with Alternating Current Interference in Carbonate/Bicarbonate Solution

verfasst von: M. Zhu, C. L. Zhang, Y. F. Yuan, S. Y. Guo, J.Pan

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 1/2023

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Abstract

The effect of different AC current densities on the corrosion behavior and mechanism of CoCrNi MEA in carbonate/bicarbonate solution was evaluated by a series of corrosion test methods. The results reveal that the interference of AC damages the internal structure of the passive film, increases its defect amount, and reduces the stability and protection of the film. With the increase in iAC, the corrosion rate of the MEA apparently increases, and the corrosion form is evoluted from pitting corrosion to general corrosion. In particular, the more severe corrosion occurs at 150 A/m2, which is attributed to a large number of H atoms distributed on the surface of the MEA. In addition, the formation of pitting is mainly due to the selective dissolution of Co element, while Co and Ni elements in the oxide are selectively dissolved in the corrosion process.

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Metadaten
Titel
The Corrosion Behavior of CoCrNi Medium Entropy Alloy with Alternating Current Interference in Carbonate/Bicarbonate Solution
verfasst von
M. Zhu
C. L. Zhang
Y. F. Yuan
S. Y. Guo
J.Pan
Publikationsdatum
20.06.2022
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 1/2023
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-022-07059-x

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