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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 10/2015

01.10.2015 | Original Contribution

Thermo-sensitive colloidal crystals composed of monodisperse colloidal silica- and poly(N-isopropyl acrylamide) gel spheres

verfasst von: Daisuke Suzuki, Kiyoshi Shibata, Akira Tsuchida, Tsuneo Okubo

Erschienen in: Colloid and Polymer Science | Ausgabe 10/2015

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Abstract

Thermo-sensitive colloidal crystals were prepared simply and conveniently by mixing of colloidal silica spheres with a series of thermo-sensitive gel spheres, poly (N-isopropyl acrylamide) (pNIPAm, 225~1500 nm in hydrodynamic diameter, 0.5~5 mol% in degree of cross-linking and at 20~45 °C) in the deionized aqueous suspension. The thermo-reversible change in the lattice spacing of colloidal crystals of monodispersed silica spheres (CS83, 103 nm in diameter) depends on the size of the admixed pNIPAm. For gel spheres with similar or less than that of the silica spheres, the lattice spacing decreased with rising temperature. On the other hand, the spacing increased with temperature for the mixtures with pNIPAm spheres of larger than the size of the silica spheres. A mechanism, which is able to explain properly the several experiments including the present work, is proposed, i.e., balancing between the weak adsorption and segregation effects of silica with gel spheres.
Vorheriger Artikel Adsorption of cationic dye from water using thermo-sensitive colloid composed of methylcellulose and sodium alginate
Nächster Artikel Liquid crystal sensor for the detection of acetylcholine using acetylcholinesterase immobilized on a nanostructured polymeric surface

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Metadaten
Titel
Thermo-sensitive colloidal crystals composed of monodisperse colloidal silica- and poly(N-isopropyl acrylamide) gel spheres
verfasst von
Daisuke Suzuki
Kiyoshi Shibata
Akira Tsuchida
Tsuneo Okubo
Publikationsdatum
01.10.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 10/2015
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-015-3661-1

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