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Erschienen in: Rare Metals 6/2017

06.04.2017

Tribological behaviour of biomedical Ti–Zr-based shape memory alloys

verfasst von: Wen-Tao Qu, Xu-Guang Sun, Bi-Fei Yuan, Kang-Ming Li, Zhen-Guo Wang, Yan Li

Erschienen in: Rare Metals | Ausgabe 6/2017

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Abstract

The tribological behaviour of Ti–30Zr, Ti–20Zr–10Nb and Ti–19Zr–10Nb–1Fe alloys was investigated using reciprocating friction and wear tests. X-ray diffraction (XRD) results indicate that Ti–30Zr, Ti–20Zr–10Nb and Ti–19Zr–10Nb–1Fe alloys are composed of hexagonal α′-martensite, orthorhombic α″-martensite and bcc β phases, respectively. Ti–30Zr alloy has the highest hardness of HV (273.1 ± 9.3), while Ti–20Zr–10Nb alloy exhibits the lowest hardness of HV (235.2 ± 20.4) among all the alloys. The tribological results indicate that Ti–30Zr alloy shows the best wear resistance among these alloys, corresponding to the minimum average friction coefficient of 0.052 and the lowest wear rate of 6.4 × 10−4 mm3·N−1·m−1. Ti–20Zr–10Nb alloy displays better wear resistance than Ti–19Zr–10Nb–1Fe alloy, because the iron oxide is easy to fall off and less Nb2O5 films form on the worn surface of the latter. Delamination and abrasive wear in association with adhesive wear are the main wear mechanism of these alloys.

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Literatur
[1]
Zurück zum Zitat Yu GH, Xu YL, Liu ZH, Qiu HM, Zhu ZY, Huang XP, Pan LQ. Recent progress in Heusler-type magnetic shape memory alloys. Rare Met. 2015;34(8):527.CrossRef Yu GH, Xu YL, Liu ZH, Qiu HM, Zhu ZY, Huang XP, Pan LQ. Recent progress in Heusler-type magnetic shape memory alloys. Rare Met. 2015;34(8):527.CrossRef
[2]
Zurück zum Zitat Xie JX, Liu JL, Huang HY. Structure design of high-performance Cu-based shape memory alloys. Rare Met. 2015;34(9):607.CrossRef Xie JX, Liu JL, Huang HY. Structure design of high-performance Cu-based shape memory alloys. Rare Met. 2015;34(9):607.CrossRef
[3]
Zurück zum Zitat Elahinia M, Moghaddam NS, Andani MT, Amerinatanzi A, Bimber BA, Hamilton RF. Fabrication of NiTi through additive manufacturing: a review. Prog Mater Sci. 2016;83:630.CrossRef Elahinia M, Moghaddam NS, Andani MT, Amerinatanzi A, Bimber BA, Hamilton RF. Fabrication of NiTi through additive manufacturing: a review. Prog Mater Sci. 2016;83:630.CrossRef
[4]
Zurück zum Zitat Liu FS, Ding Z, Li Y, Xu HB. Phase transformation behaviours and mechanical properties of TiNiMo shape memory alloys. Intermetallics. 2005;13(3–4):357.CrossRef Liu FS, Ding Z, Li Y, Xu HB. Phase transformation behaviours and mechanical properties of TiNiMo shape memory alloys. Intermetallics. 2005;13(3–4):357.CrossRef
[5]
Zurück zum Zitat Li Y, Xin Y, Jiang CB, Xu HB. Mechanical and shape memory properties of Ni54Mn25Ga21 high temperature shape memory alloy. Mater Sci Eng A. 2006;438–440:978.CrossRef Li Y, Xin Y, Jiang CB, Xu HB. Mechanical and shape memory properties of Ni54Mn25Ga21 high temperature shape memory alloy. Mater Sci Eng A. 2006;438–440:978.CrossRef
[6]
Zurück zum Zitat Cui LS, Li Y, Zheng YJ, Yang DZ. Two stage recovery strain of prestrained TiNi shape memory alloy after phase transformations under constraint. Mater Lett. 2001;47(4–5):286.CrossRef Cui LS, Li Y, Zheng YJ, Yang DZ. Two stage recovery strain of prestrained TiNi shape memory alloy after phase transformations under constraint. Mater Lett. 2001;47(4–5):286.CrossRef
[7]
Zurück zum Zitat Duerig T, Pelton A, Stöckel D. An overview of nitinol medical applications. Mater Sci Eng A. 1999;273–275:149.CrossRef Duerig T, Pelton A, Stöckel D. An overview of nitinol medical applications. Mater Sci Eng A. 1999;273–275:149.CrossRef
[8]
Zurück zum Zitat Jani JM, Leary M, Subic A, Gibson MA. A review of shape memory alloy research, applications and opportunities. Mater Des. 2014;56:1078.CrossRef Jani JM, Leary M, Subic A, Gibson MA. A review of shape memory alloy research, applications and opportunities. Mater Des. 2014;56:1078.CrossRef
[9]
Zurück zum Zitat Ion R, Luculescu C, Cimpean A, Marx P, Gordin DM, Gloriant T. Nitride coating enhances endothelialization on biomedical NiTi shape memory alloy. Mater Sci Eng C. 2016;62:686.CrossRef Ion R, Luculescu C, Cimpean A, Marx P, Gordin DM, Gloriant T. Nitride coating enhances endothelialization on biomedical NiTi shape memory alloy. Mater Sci Eng C. 2016;62:686.CrossRef
[10]
Zurück zum Zitat Zhao TT, Li Y, Zhao XQ, Chen H, Zhang T. Ni ion release, osteoblasts-materials interactions and hemocompatibility of hafnium implanted NiTi alloy. J Biomed Mater Res B. 2012;100(3):1227. Zhao TT, Li Y, Zhao XQ, Chen H, Zhang T. Ni ion release, osteoblasts-materials interactions and hemocompatibility of hafnium implanted NiTi alloy. J Biomed Mater Res B. 2012;100(3):1227.
[11]
Zurück zum Zitat Zhao TT, Yang RX, Zhong C, Li Y, Xiang Y. Effective inhibition of nickel release by tantalum-implanted TiNi alloy and its cyto-compatibility evaluation in vitro. J Mater Sci. 2011;46(8):2529.CrossRef Zhao TT, Yang RX, Zhong C, Li Y, Xiang Y. Effective inhibition of nickel release by tantalum-implanted TiNi alloy and its cyto-compatibility evaluation in vitro. J Mater Sci. 2011;46(8):2529.CrossRef
[12]
Zurück zum Zitat Ikarashi Y, Toyoda K, Kobayashi E, Doi H, Yoneyama T, Hamanaka H, Tsuchiya T. Improved biocompatibility of titanium–zirconium (Ti–Zr) alloy: tissue reaction and sensitization to Ti–Zr alloy compared with pure Ti and Zr in rat implantation study. Mater Trans. 2005;46(10):2260.CrossRef Ikarashi Y, Toyoda K, Kobayashi E, Doi H, Yoneyama T, Hamanaka H, Tsuchiya T. Improved biocompatibility of titanium–zirconium (Ti–Zr) alloy: tissue reaction and sensitization to Ti–Zr alloy compared with pure Ti and Zr in rat implantation study. Mater Trans. 2005;46(10):2260.CrossRef
[13]
Zurück zum Zitat Ho WF, Chen WK, Wu SC, Hsu HC. Structure, mechanical properties, and grindability of dental Ti–Zr alloys. J Mater Sci Mater Med. 2008;19(10):3179.CrossRef Ho WF, Chen WK, Wu SC, Hsu HC. Structure, mechanical properties, and grindability of dental Ti–Zr alloys. J Mater Sci Mater Med. 2008;19(10):3179.CrossRef
[14]
Zurück zum Zitat Kobayashi E, Doi H, Yoneyama T, Hamanaka H. Influence of aging heat treatment on mechanical properties of biomedical Ti–Zr based ternary alloys containing niobium. J Mater Sci Mater Med. 1998;9(11):625.CrossRef Kobayashi E, Doi H, Yoneyama T, Hamanaka H. Influence of aging heat treatment on mechanical properties of biomedical Ti–Zr based ternary alloys containing niobium. J Mater Sci Mater Med. 1998;9(11):625.CrossRef
[15]
Zurück zum Zitat Li Y, Cui Y, Zhang F, Xu HB. Shape memory behaviour in Ti–Zr alloys. Scr Mater. 2011;64(6):584.CrossRef Li Y, Cui Y, Zhang F, Xu HB. Shape memory behaviour in Ti–Zr alloys. Scr Mater. 2011;64(6):584.CrossRef
[16]
Zurück zum Zitat Kim JI, Kim HY, Inamura T, Hosoda H, Miyazaki S. Shape memory characteristics of Ti–22Nb–(2–8)Zr (at.%) biomedical alloys. Mater Sci Eng A. 2005;403(1–2):334.CrossRef Kim JI, Kim HY, Inamura T, Hosoda H, Miyazaki S. Shape memory characteristics of Ti–22Nb–(2–8)Zr (at.%) biomedical alloys. Mater Sci Eng A. 2005;403(1–2):334.CrossRef
[17]
Zurück zum Zitat Cui Y, Li Y, Luo K, Xu HB. Microstructure and shape memory effect of Ti–20Zr–10Nb alloy. Mater Sci Eng A. 2010;527(3):652.CrossRef Cui Y, Li Y, Luo K, Xu HB. Microstructure and shape memory effect of Ti–20Zr–10Nb alloy. Mater Sci Eng A. 2010;527(3):652.CrossRef
[18]
Zurück zum Zitat Xue PF, Li Y, Li KM, Zhang DY, Zhou CG. Superelasticity, corrosion resistance and biocompatibility of the Ti–19Zr–10Nb–1Fe alloy. Mater Sci Eng C. 2015;50:179.CrossRef Xue PF, Li Y, Li KM, Zhang DY, Zhou CG. Superelasticity, corrosion resistance and biocompatibility of the Ti–19Zr–10Nb–1Fe alloy. Mater Sci Eng C. 2015;50:179.CrossRef
[19]
Zurück zum Zitat Xue PF, Li Y, Zhang F, Zhou CG. Shape memory effect and phase transformations of Ti–19.5Zr–10Nb–0.5Fe alloy. Scr Mater. 2015;101:99.CrossRef Xue PF, Li Y, Zhang F, Zhou CG. Shape memory effect and phase transformations of Ti–19.5Zr–10Nb–0.5Fe alloy. Scr Mater. 2015;101:99.CrossRef
[20]
Zurück zum Zitat Xiong CY, Yao L, Yuan BF, Qu WT, Li Y. Strain induced martensite stabilization and shape memory effect of Ti–20Zr–10Nb–4Ta alloy. Mater Sci Eng A. 2016;658:28.CrossRef Xiong CY, Yao L, Yuan BF, Qu WT, Li Y. Strain induced martensite stabilization and shape memory effect of Ti–20Zr–10Nb–4Ta alloy. Mater Sci Eng A. 2016;658:28.CrossRef
[21]
Zurück zum Zitat Yu ZG, Xiong CY, Xue PF, Li Y, Yuan BF, Qu WT. Shape memory behavior of Ti–20Zr–10Nb–5Al alloy subjected to annealing treatment. Rare Met. 2016;35(11):831.CrossRef Yu ZG, Xiong CY, Xue PF, Li Y, Yuan BF, Qu WT. Shape memory behavior of Ti–20Zr–10Nb–5Al alloy subjected to annealing treatment. Rare Met. 2016;35(11):831.CrossRef
[22]
Zurück zum Zitat Hao YL, Li SJ, Yang R. Biomedical titanium alloys and their additive manufacturing. Rare Met. 2016;35(9):661.CrossRef Hao YL, Li SJ, Yang R. Biomedical titanium alloys and their additive manufacturing. Rare Met. 2016;35(9):661.CrossRef
[23]
Zurück zum Zitat Correa DRN, Vicente FB, Donato TAG, Arana-Chavez VE, Buzalaf MAR, Grandini CR. The effect of the solute on the structure, selected mechanical properties, and biocompatibility of Ti–Zr system alloys for dental applications. Mater Sci Eng C. 2014;34:354.CrossRef Correa DRN, Vicente FB, Donato TAG, Arana-Chavez VE, Buzalaf MAR, Grandini CR. The effect of the solute on the structure, selected mechanical properties, and biocompatibility of Ti–Zr system alloys for dental applications. Mater Sci Eng C. 2014;34:354.CrossRef
[24]
Zurück zum Zitat Li Y, Zhang F, Zhao TT, Tang M, Liu Y. Enhanced wear resistance of NiTi alloy by surface modification with Nb ion implantation. Rare Met. 2014;33(3):244.CrossRef Li Y, Zhang F, Zhao TT, Tang M, Liu Y. Enhanced wear resistance of NiTi alloy by surface modification with Nb ion implantation. Rare Met. 2014;33(3):244.CrossRef
[25]
Zurück zum Zitat Zhao TT, Li Y, Liu Y, Zhao XQ. Nano-hardness, wear resistance and pseudoelasticity of hafnium implanted NiTi shape memory alloy. J Mech Behav Biomed Mater. 2012;13:174.CrossRef Zhao TT, Li Y, Liu Y, Zhao XQ. Nano-hardness, wear resistance and pseudoelasticity of hafnium implanted NiTi shape memory alloy. J Mech Behav Biomed Mater. 2012;13:174.CrossRef
[26]
Zurück zum Zitat Wang ZG, Huang WJ, Ma YL. Micro-scale abrasive wear behaviour of medical implant material Ti–25Nb–3Mo–3Zr–2Sn alloy on various friction pairs. Mater Sci Eng C. 2014;42:211.CrossRef Wang ZG, Huang WJ, Ma YL. Micro-scale abrasive wear behaviour of medical implant material Ti–25Nb–3Mo–3Zr–2Sn alloy on various friction pairs. Mater Sci Eng C. 2014;42:211.CrossRef
[27]
Zurück zum Zitat Guo S, Zheng Q, Hou XL, Cheng XN, Zhao XQ. Wear response of metastable β-type Ti–25Nb–2Mo–4Sn alloy for biomedical applications. Rare Met. 2015;34(8):564.CrossRef Guo S, Zheng Q, Hou XL, Cheng XN, Zhao XQ. Wear response of metastable β-type Ti–25Nb–2Mo–4Sn alloy for biomedical applications. Rare Met. 2015;34(8):564.CrossRef
[28]
Zurück zum Zitat Sak A, Moskalewicz T, Zimowski S, Cieniek Ł, Dubiel B, Radziszewska A, Kot M, Łukaszczyk A. Influence of polyetheretherketone coatings on the Ti–13Nb–13Zr titanium alloy’s bio-tribological properties and corrosion resistance. Mater Sci Eng C. 2016;63:52.CrossRef Sak A, Moskalewicz T, Zimowski S, Cieniek Ł, Dubiel B, Radziszewska A, Kot M, Łukaszczyk A. Influence of polyetheretherketone coatings on the Ti–13Nb–13Zr titanium alloy’s bio-tribological properties and corrosion resistance. Mater Sci Eng C. 2016;63:52.CrossRef
[29]
Zurück zum Zitat Wang ZG, Li Y, Huang WJ, Chen XL, He HR. Micro-abrasion–corrosion behaviour of a biomedical Ti–25Nb–3Mo–3Zr–2Sn alloy in simulated physiological fluid. J Mech Behav Biomed Mater. 2016;63:361.CrossRef Wang ZG, Li Y, Huang WJ, Chen XL, He HR. Micro-abrasion–corrosion behaviour of a biomedical Ti–25Nb–3Mo–3Zr–2Sn alloy in simulated physiological fluid. J Mech Behav Biomed Mater. 2016;63:361.CrossRef
[30]
Zurück zum Zitat Zhang P, Li SX, Zhang ZF. General relationship between strength and hardness. Mater Sci Eng A. 2011;529:62.CrossRef Zhang P, Li SX, Zhang ZF. General relationship between strength and hardness. Mater Sci Eng A. 2011;529:62.CrossRef
[31]
Zurück zum Zitat Dahm KL. Fatigue-like failure of thermally oxidised titanium in reciprocating pin-on-plate wear tests. Wear. 2009;267(1–4):409.CrossRef Dahm KL. Fatigue-like failure of thermally oxidised titanium in reciprocating pin-on-plate wear tests. Wear. 2009;267(1–4):409.CrossRef
[32]
Zurück zum Zitat Valero VC, Olmo JA, Igual MA. Adsorption of bovine serum albumin on CoCrMo surface: effect of temperature and protein concentration. Colloid Surf B. 2010;80(1):1.CrossRef Valero VC, Olmo JA, Igual MA. Adsorption of bovine serum albumin on CoCrMo surface: effect of temperature and protein concentration. Colloid Surf B. 2010;80(1):1.CrossRef
[33]
Zurück zum Zitat Zhao TT, Li Y, Xiang Y, Zhao XQ, Zhang T. Surface characteristics, nano-indentation and corrosion behaviour of Nb implanted NiTi alloy. Surf Coat Technol. 2011;205(19):4404.CrossRef Zhao TT, Li Y, Xiang Y, Zhao XQ, Zhang T. Surface characteristics, nano-indentation and corrosion behaviour of Nb implanted NiTi alloy. Surf Coat Technol. 2011;205(19):4404.CrossRef
[34]
Zurück zum Zitat Magaziner RS, Jain VK, Mall S. Wear characterization of Ti–6Al–4V under fretting-reciprocating sliding conditions. Wear. 2008;264(11–12):1002.CrossRef Magaziner RS, Jain VK, Mall S. Wear characterization of Ti–6Al–4V under fretting-reciprocating sliding conditions. Wear. 2008;264(11–12):1002.CrossRef
[35]
Zurück zum Zitat Ansari F, Ries M, Pruitt L. Effect of processing, sterilization and crosslinking on UHMWPE fatigue fracture and fatigue wear mechanisms in joint arthroplasty. J Mech Behav Mater. 2016;53:329.CrossRef Ansari F, Ries M, Pruitt L. Effect of processing, sterilization and crosslinking on UHMWPE fatigue fracture and fatigue wear mechanisms in joint arthroplasty. J Mech Behav Mater. 2016;53:329.CrossRef
[36]
Zurück zum Zitat Korres S, Feser T, Dienwiebel M. In situ observation of wear particle formation on lubricated sliding surfaces. Acta Mater. 2012;60(1):420.CrossRef Korres S, Feser T, Dienwiebel M. In situ observation of wear particle formation on lubricated sliding surfaces. Acta Mater. 2012;60(1):420.CrossRef
[37]
Zurück zum Zitat Suh NP, Jahanmir S, Abrahamson EP, Turner APL. Further investigation of the delamination theory of wear. J Lubr Technol. 1974;96(4):631.CrossRef Suh NP, Jahanmir S, Abrahamson EP, Turner APL. Further investigation of the delamination theory of wear. J Lubr Technol. 1974;96(4):631.CrossRef
Metadaten
Titel
Tribological behaviour of biomedical Ti–Zr-based shape memory alloys
verfasst von
Wen-Tao Qu
Xu-Guang Sun
Bi-Fei Yuan
Kang-Ming Li
Zhen-Guo Wang
Yan Li
Publikationsdatum
06.04.2017
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 6/2017
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-017-0882-0

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