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16.11.2022 | Original Article

ZnO/PANI nanoflake arrays sensor for ultra-low concentration and rapid detection of NO₂ at room temperature

verfasst von: Qiu-Yue Zheng, Meng Yang, Xin Dong, Xian-Fa Zhang, Xiao-Li Cheng, Li-Hua Huo, Zoltán Major, Ying-Ming Xu

Erschienen in: Rare Metals | Ausgabe 2/2023

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Abstract

With the development of environmental monitoring, it is urgent to establish NO₂ sensor with good sensing performance. Compared with the traditional NO₂ sensors made of metal oxides, NO₂ sensors made of n-p heterostructure nanocomposites have good sensing performance in detection limit and operating temperature. ZnO nanoflake arrays with polyaniline film grown on the surface were prepared on ceramic tubes by hydrothermal and vapor diffusion method. The gas-phase diffusion method can control the heterostructure by adjusting the diffusion time. At room temperature (25 °C), the construction of rich n-p heterogeneous interface enables the sensor prepared by the nanocomposite to respond to NO₂, showing the sensing performance with the response value of 28.00 to 10.00 × 10^–6 NO₂; the detection limit improved to 0.01 × 10^–6 and the recovery time of 18 s. In this work, the sensing mechanism of NO₂ at heterogeneous interface is analyzed, which provides a promising material for the detection of low concentration NO₂ at room temperature.

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Titel: ZnO/PANI nanoflake arrays sensor for ultra-low concentration and rapid detection of NO2 at room temperature
verfasst von: Qiu-Yue Zheng
Meng Yang
Xin Dong
Xian-Fa Zhang
Xiao-Li Cheng
Li-Hua Huo
Zoltán Major
Ying-Ming Xu
Publikationsdatum: 16.11.2022
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 2/2023
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-022-02149-0

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