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Journal of Materials Engineering and Performance

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23.05.2022 | Technical Article

Effect of Black Phosphorus Oxidation on Tribological Properties of Polytetrafluoroethylene-Based Composites

verfasst von: Zheng Wang, Lina Zhu, Guoxin Xie, Xiaoyong Ren

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 12/2022

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Abstract

Black phosphorus (BP) as an emerging two-dimensional material has been found that it possesses excellent potential applications in a variety of fields. Recently, it has been also proved that BP can exhibit excellent lubricating properties when it was used as water- or oil-based lubricant additive. In the present work, in order to explore the tribological properties of BP nanoflakes used as the solid filler in polytetrafluoroethylene (PTFE), spark plasma sintering (SPS) was used to prepare the BP/PTFE composites. Meanwhile, in consideration of the characteristics of BP easy to be oxidized, BP was actively oxidized to prepare the degraded BP (d-BP)/PTFE composites. Then Si₃N₄ balls were used as counterpart balls to conduct tribological experiments. The results of tribological experiment showed d-BP/PTFE composites with a d-BP content of 5 wt.% exhibited the best tribological properties under dry sliding and water environment condition. The characterizations and analyses of the counterpart balls and worn surfaces demonstrated that a layer of transfer film composed of phosphorus oxide reduced the coefficient of friction (COF) and wear rate. Besides, when the composites were used in an environment of water, the phosphorus oxide on the surface can dissolve in water and form a hydrogen bond network and thus further reduced friction.

Vorheriger Artikel Effect of Drag Finish Post-processing on Surface Integrity and Wear Behavior of Ti-6Al-4V Fabricated by Laser Powder Bed Fusion Additive Manufacturing

Nächster Artikel Reciprocating Wear of Ti-TiB In Situ Composites Synthesized via Vacuum Arc Melting

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Titel: Effect of Black Phosphorus Oxidation on Tribological Properties of Polytetrafluoroethylene-Based Composites
verfasst von: Zheng Wang
Lina Zhu
Guoxin Xie
Xiaoyong Ren
Publikationsdatum: 23.05.2022
Verlag: Springer US
Erschienen in: Journal of Materials Engineering and Performance / Ausgabe 12/2022
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-022-07005-x

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