Enhancement in photovoltaic properties of Nd:SnS films prepared by low-cost NSP method

The inner transition metal (ITM) neodymium (Nd)-doped tin sulfide (Nd:SnS) thin films with various Nd concentrations were coated by nebulizer spray pyrolysis (NSP) technique at 350 °C. All the coated films were analyzed for their structural, optical and photoelectrical properties. X-ray diffractometer (XRD) study showed (111) direction as the highly preferred orientation with orthorhombic crystal structure for all the films. The intensity of the peaks was found to increase until 5 at% Nd doping and then reduced for higher (7 at% Nd) doping concentration. Atomic force microscopic (AFM) images of the films proclaimed an increase in the surface and line roughness of the films by increasing Nd concentrations. Optical analysis on the films showed a variation in energy gap from 2.05 to 1.69 eV when the doping concentration increased from 0 at% to 7 at%. At 5 at% Nd doping, the photoluminescence (PL) spectra displayed a single strong emission peak at 723.1 nm with enhanced intensity corresponding to near-band-edge emission. All the SnS thin films exhibited p-type behavior with the lowest resistivity of ~ 4.311 Ω·cm and high carrier concentrations of ~ 1.441 × 10¹⁷ cm⁻³ for 5 at% Nd doping level as observed from Hall effect studies. Furthermore, fluorine-doped tin oxide (FTO)/n-CdS/p-Nd:SnS hetero-junction solar cells were prepared and the current–voltage curve in dark and light condition was obtained for the device. An efficiency of 0.135% was observed for the solar cell fabricated with 5 at% Nd-doped SnS thin film.