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Erschienen in: Mechanics of Composite Materials 4/2023

02.09.2023

Influence of Polyethersulfone on the Fracture Toughness of Epoxy Matrices and Reinforced Plastics on Their Basis

verfasst von: V. I. Solodilov, I. V. Tretyakov, T. V. Petrova, A. V. Kireynov, R. A. Korokhin, G. Y. Yurkov

Erschienen in: Mechanics of Composite Materials | Ausgabe 4/2023

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Abstract

The physical-mechanical properties of epoxy matrices modified with polyethersulfone (PES) and unidirectional glass- and carbon-fiber-reinforced plastics (GFRP and CFRP) based on them were investigated. The fracture toughness of epoxy matrices modified with 20 wt% PES, increased by 4.3 times. The delamination energy of GFRP and CFRP with this content of PES in the matrix increases by 50 and 65%, respectively. A correlation between the fracture toughness of modified matrices and the delamination toughness of GFRP and CFRP was established, and the influence of structure of the matrices on the fracture toughness of the reinforced plastics was demonstrated. A significant increase in the fracture toughness of the matrices and reinforced plastics was also observed during the formation of extended phases enriched with PES.

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Literatur
1.
Zurück zum Zitat E. O. Ozgul and M. H. Ozkul, “Effects of epoxy, hardener, and diluent types on the workability of epoxy mixtures,” Constr. Build. Mater., 158, 369-377 (2018).CrossRef E. O. Ozgul and M. H. Ozkul, “Effects of epoxy, hardener, and diluent types on the workability of epoxy mixtures,” Constr. Build. Mater., 158, 369-377 (2018).CrossRef
2.
Zurück zum Zitat Y. Li, B. Li, and W. Chen, “A study on the reactive diluent for the solvent-free epoxy anticorrosive coating, J. Chem. Pharma. Res., 6, No. 7, 2466-2469 (2014). Y. Li, B. Li, and W. Chen, “A study on the reactive diluent for the solvent-free epoxy anticorrosive coating, J. Chem. Pharma. Res., 6, No. 7, 2466-2469 (2014).
3.
Zurück zum Zitat L. Shen, Y. Wang, Q. Zhao, F. Luo, J. Chen, M. Lu, L. Liang, K. Wu, and J. Shi, “Influence of a long-side-chain-containing reactive diluent on the structure and mechanical properties of UV-cured films,” Polymer Int., 65, No. 10, 1150-1156 (2016).CrossRef L. Shen, Y. Wang, Q. Zhao, F. Luo, J. Chen, M. Lu, L. Liang, K. Wu, and J. Shi, “Influence of a long-side-chain-containing reactive diluent on the structure and mechanical properties of UV-cured films,” Polymer Int., 65, No. 10, 1150-1156 (2016).CrossRef
4.
Zurück zum Zitat Animesh Sinha, Nazrul Islam Khan, Subhankar Das, Jiawei Zhang, and Sudipta Halder, “Effect of reactive and nonreactive diluent on mechanical properties of epoxy resin,” High Perf. Polym., 30, 1159-1168 (2018).CrossRef Animesh Sinha, Nazrul Islam Khan, Subhankar Das, Jiawei Zhang, and Sudipta Halder, “Effect of reactive and nonreactive diluent on mechanical properties of epoxy resin,” High Perf. Polym., 30, 1159-1168 (2018).CrossRef
5.
Zurück zum Zitat M. Khalina, M. H. Beheshty, and A. Salimi, “The effect of reactive diluent on mechanical properties and microstructure of epoxy resins,” Polym. bull., 76, 3905-3927 (2019).CrossRef M. Khalina, M. H. Beheshty, and A. Salimi, “The effect of reactive diluent on mechanical properties and microstructure of epoxy resins,” Polym. bull., 76, 3905-3927 (2019).CrossRef
6.
Zurück zum Zitat M. N. Kopitsyna, I. V. Bessonov, and S. V. Kotomin, “Fracture strength of epoxy binders modified by thermoplastic polysulfone and furfural-acetone resin,” Engineer. J. Sci. Innovat., 60, No. 12, 1-9 (2016). M. N. Kopitsyna, I. V. Bessonov, and S. V. Kotomin, “Fracture strength of epoxy binders modified by thermoplastic polysulfone and furfural-acetone resin,” Engineer. J. Sci. Innovat., 60, No. 12, 1-9 (2016).
7.
Zurück zum Zitat K. A. Al-Shiblawi, V. F. Pershin, and V. P. Yartsev, “Modification of epoxy resins: modern condition and prospects. Part I. Modification of Nanoparticles,” Adv. Mater. Technol., No. 2, 68-78 (2018). K. A. Al-Shiblawi, V. F. Pershin, and V. P. Yartsev, “Modification of epoxy resins: modern condition and prospects. Part I. Modification of Nanoparticles,” Adv. Mater. Technol., No. 2, 68-78 (2018).
8.
Zurück zum Zitat K. A. Al-Shiblawi, V. F. Pershin, and V. P. Yartsev, “Modification of epoxy resins: modern condition and prospects. Part II. Graphene and graphene oxide modification,” Adv. Mater. Technol., No. 4, 42-53 (2018). K. A. Al-Shiblawi, V. F. Pershin, and V. P. Yartsev, “Modification of epoxy resins: modern condition and prospects. Part II. Graphene and graphene oxide modification,” Adv. Mater. Technol., No. 4, 42-53 (2018).
9.
Zurück zum Zitat A. S. Mostovoi, A. S. Nurtazina, and Yu. A. Kadykova, “Epoxy composites with increased operational characteristics, filled with dispersed mineral fillers,” Proceedings of VSUET, 80, No. 3, 330-335 (2018). A. S. Mostovoi, A. S. Nurtazina, and Yu. A. Kadykova, “Epoxy composites with increased operational characteristics, filled with dispersed mineral fillers,” Proceedings of VSUET, 80, No. 3, 330-335 (2018).
10.
Zurück zum Zitat T. S. Kurkin, E. P. Tikunova, A. V. Solopchenko, M. Yu. Yablokova, and A. N. Ozerin Polymer composite materials based on thermoset epoxy binders modified with diamond-containing nanofillers,” Polym. Sci. Series S., 58, 50-61 (2016). T. S. Kurkin, E. P. Tikunova, A. V. Solopchenko, M. Yu. Yablokova, and A. N. Ozerin Polymer composite materials based on thermoset epoxy binders modified with diamond-containing nanofillers,” Polym. Sci. Series S., 58, 50-61 (2016).
11.
Zurück zum Zitat E. M. Nurullaev, “Influence of high-frequency radiation on the deformation behavior of composites based on low-molecular rubbers filled with silicon dioxide,” Mech. Compos. Mater., 56, No. 3, 329-338 (2020).CrossRef E. M. Nurullaev, “Influence of high-frequency radiation on the deformation behavior of composites based on low-molecular rubbers filled with silicon dioxide,” Mech. Compos. Mater., 56, No. 3, 329-338 (2020).CrossRef
12.
Zurück zum Zitat A. Drah, N. Z. Tomić, T. Kovačević, V. Djokić, M. Tomić, R. J. Heinemann, and A. Marinkovićet, “Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness,” Mech. Compos. Mater., 56, No. 2, 249-260 (2020).CrossRef A. Drah, N. Z. Tomić, T. Kovačević, V. Djokić, M. Tomić, R. J. Heinemann, and A. Marinkovićet, “Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness,” Mech. Compos. Mater., 56, No. 2, 249-260 (2020).CrossRef
13.
Zurück zum Zitat M. M. Buzmakova, V. G. Gilev, A. F. Merzlyakov, and S.V. Rusakov, “Physical properties of an epoxy composite modified by C60 fullerenes,” Mech. Compos. Mater., 54, No. 4, 545-552 (2018).CrossRef M. M. Buzmakova, V. G. Gilev, A. F. Merzlyakov, and S.V. Rusakov, “Physical properties of an epoxy composite modified by C60 fullerenes,” Mech. Compos. Mater., 54, No. 4, 545-552 (2018).CrossRef
14.
Zurück zum Zitat S. V. Smirnov, I. A. Veretennikova, V. M. Fomin, A. A. Filippov, and T. A. Brusentseva, “Studying the viscoelastic properties of an epoxy resin strengthened with silicon dioxide nanoparticles by instrumented microindentation,” Mech. Compos. Mater., 55, No. 3, 337-348 (2019).CrossRef S. V. Smirnov, I. A. Veretennikova, V. M. Fomin, A. A. Filippov, and T. A. Brusentseva, “Studying the viscoelastic properties of an epoxy resin strengthened with silicon dioxide nanoparticles by instrumented microindentation,” Mech. Compos. Mater., 55, No. 3, 337-348 (2019).CrossRef
15.
Zurück zum Zitat O. Yu. Bogomolova, I. R. Biktagirova, M. P. Danilaev, M. A. Klabukov, Yu. E. Polsky, Pillai Saju, and A. A. Tsentsevitsky, “Effect of adhesion between submicron filler particles and a polymeric matrix on the structure and mechanical properties of epoxy-resin-based compositions,” Mech. Compos. Mater., 53, No. 1, 117-122 (2017). O. Yu. Bogomolova, I. R. Biktagirova, M. P. Danilaev, M. A. Klabukov, Yu. E. Polsky, Pillai Saju, and A. A. Tsentsevitsky, “Effect of adhesion between submicron filler particles and a polymeric matrix on the structure and mechanical properties of epoxy-resin-based compositions,” Mech. Compos. Mater., 53, No. 1, 117-122 (2017).
16.
Zurück zum Zitat A. Białkowska, M. Bakar, and M. Przybyłek, “Effect of nonisocyanate polyurethane and nanoclay on the mechanical properties of an epoxy resin,” Mech. Compos. Mater., 54, No. 5, 665-674 (2018).CrossRef A. Białkowska, M. Bakar, and M. Przybyłek, “Effect of nonisocyanate polyurethane and nanoclay on the mechanical properties of an epoxy resin,” Mech. Compos. Mater., 54, No. 5, 665-674 (2018).CrossRef
18.
Zurück zum Zitat Z. Ay and M. Tanoğlu, “The effect of single-walled carbon nanotube (SWCNT) concentration on the mechanical and rheological behavior of epoxy matrix,” Mech. Compos. Mater., 56, No. 4, 523-532 (2020).CrossRef Z. Ay and M. Tanoğlu, “The effect of single-walled carbon nanotube (SWCNT) concentration on the mechanical and rheological behavior of epoxy matrix,” Mech. Compos. Mater., 56, No. 4, 523-532 (2020).CrossRef
19.
Zurück zum Zitat J. Wang, R. Liu, and X. Jian, “Introduction to epoxy/thermoplastic blends,” Handbook of epoxy blends, 429-458 (2017). J. Wang, R. Liu, and X. Jian, “Introduction to epoxy/thermoplastic blends,” Handbook of epoxy blends, 429-458 (2017).
20.
Zurück zum Zitat T. V. Brantseva, S. V. Antonov, N. M. Smirnova, V. I. Solodilov, R. A. Korohin, I. Y. Gorbunova, and A. V. Shapagin, “Epoxy modification with poly(vinyl acetate) and poly(vinyl butyral). I. Structure, thermal, and mechanical characteristics,” J. Appl. Polym. Sci., 133, No. 41, 44081-44094 (2016).CrossRef T. V. Brantseva, S. V. Antonov, N. M. Smirnova, V. I. Solodilov, R. A. Korohin, I. Y. Gorbunova, and A. V. Shapagin, “Epoxy modification with poly(vinyl acetate) and poly(vinyl butyral). I. Structure, thermal, and mechanical characteristics,” J. Appl. Polym. Sci., 133, No. 41, 44081-44094 (2016).CrossRef
21.
Zurück zum Zitat Y. Rosetti, P. Alcouffe, J.-P. Pascault, J.-F. Gerard, and F. Lortie, “Polyether sulfone-based epoxy toughening: from micro- to nano-phase separation via pes end-chain modification and process engineering,” Materials., 11, No. 10, 1960 (2018). Y. Rosetti, P. Alcouffe, J.-P. Pascault, J.-F. Gerard, and F. Lortie, “Polyether sulfone-based epoxy toughening: from micro- to nano-phase separation via pes end-chain modification and process engineering,” Materials., 11, No. 10, 1960 (2018).
22.
Zurück zum Zitat V. I. Solodilov, R. A. Korokhin, Yu. A. Gorbatkina, and A. M. Kuperman, “Comparison of fracture energies of epoxy-polysulfone matrices and unidirectional composites based on them,” Mech. Compos. Mater., 51, No. 2, 177-190 (2015).CrossRef V. I. Solodilov, R. A. Korokhin, Yu. A. Gorbatkina, and A. M. Kuperman, “Comparison of fracture energies of epoxy-polysulfone matrices and unidirectional composites based on them,” Mech. Compos. Mater., 51, No. 2, 177-190 (2015).CrossRef
23.
Zurück zum Zitat A. V. Shapagin, N. Yu. Budylin, A. E. Chalykh, V. I. Solodilov, R. A. Korokhin, and A. A. Poteryaev, “Phase equilibrium, morphology, and physico-mechanics in epoxy–thermoplastic mixtures with upper and lower critical solution temperatures,” Polymers, 13, No. 1, 1-12 (2021). A. V. Shapagin, N. Yu. Budylin, A. E. Chalykh, V. I. Solodilov, R. A. Korokhin, and A. A. Poteryaev, “Phase equilibrium, morphology, and physico-mechanics in epoxy–thermoplastic mixtures with upper and lower critical solution temperatures,” Polymers, 13, No. 1, 1-12 (2021).
24.
Zurück zum Zitat V. I. Solodilov and Yu. A. Gorbatkina, “Properties of unidirectional gfrps based on an epoxy resin modified with polysulphone or an epoxyurethane oligomer,” Mech. Compos. Mater., 42, No. 6, 513-526 (2006).CrossRef V. I. Solodilov and Yu. A. Gorbatkina, “Properties of unidirectional gfrps based on an epoxy resin modified with polysulphone or an epoxyurethane oligomer,” Mech. Compos. Mater., 42, No. 6, 513-526 (2006).CrossRef
25.
Zurück zum Zitat A. E. Chalykh, V. K. Gerasimov, A. E. Bukhteev, A. V. Shapagin, G. Kh. Kudryakova, T. V. Brantseva, Yu. A. Gorbatkina, and M. L. Kerber, “Compatibility and phase structure evolution in polysulfone-curable epoxy oligomer blends,” Polym. Sci. Series A., 45, No. 7, 676-685 (2003). A. E. Chalykh, V. K. Gerasimov, A. E. Bukhteev, A. V. Shapagin, G. Kh. Kudryakova, T. V. Brantseva, Yu. A. Gorbatkina, and M. L. Kerber, “Compatibility and phase structure evolution in polysulfone-curable epoxy oligomer blends,” Polym. Sci. Series A., 45, No. 7, 676-685 (2003).
26.
Zurück zum Zitat J. E. Robertson, T. C. Ward, and A. J. Hill, “Thermal mechanical, physical, and transport properties of blends of novel oligomer and thermoplastic polysulfone,” Polymer, 41, 6251-6262 (2000).CrossRef J. E. Robertson, T. C. Ward, and A. J. Hill, “Thermal mechanical, physical, and transport properties of blends of novel oligomer and thermoplastic polysulfone,” Polymer, 41, 6251-6262 (2000).CrossRef
27.
Zurück zum Zitat Crack Resistance of Cured Polymer Compositions [in Russian], P. G. Babaevsky, S. G. Kulik, M., Khimia (1991). Crack Resistance of Cured Polymer Compositions [in Russian], P. G. Babaevsky, S. G. Kulik, M., Khimia (1991).
28.
Zurück zum Zitat V. I. Solodilov, S. L. Bashenov, Yu. A. Gorbatkina, and A. M. Kuperman, “Determination of the interlaminar fracture toughness of glass-fiber-reinforced plastics on ring segments,” Mech. Compos. Mater., 39, No. 5, 401-414 (2003).CrossRef V. I. Solodilov, S. L. Bashenov, Yu. A. Gorbatkina, and A. M. Kuperman, “Determination of the interlaminar fracture toughness of glass-fiber-reinforced plastics on ring segments,” Mech. Compos. Mater., 39, No. 5, 401-414 (2003).CrossRef
29.
Zurück zum Zitat B. F. Sorensen and T. K. Jacobsen, “Large-scale bridging in composites: R-curves and bridging laws,” Compos., Part A, 29, No. 11, 1443-1451 (1998).CrossRef B. F. Sorensen and T. K. Jacobsen, “Large-scale bridging in composites: R-curves and bridging laws,” Compos., Part A, 29, No. 11, 1443-1451 (1998).CrossRef
30.
Zurück zum Zitat T. K. Jacobsen and B. F. Sorensen, “Mode I intra-laminar crack growth in composites – modeling of R-curves from measured bridging laws,” Compos., Part A, 32, No. 1, 1-11 (2001).CrossRef T. K. Jacobsen and B. F. Sorensen, “Mode I intra-laminar crack growth in composites – modeling of R-curves from measured bridging laws,” Compos., Part A, 32, No. 1, 1-11 (2001).CrossRef
31.
Zurück zum Zitat R. A. Korokhin, V. I. Solodilov, U. G. Zvereva, D. V. Solomatin, Y. A. Gorbatkina, A. V. Shapagin, and M. Y. Bamborin, “Epoxy polymers modified with polyetherimide. Part II: physicomechanical properties of modified epoxy oligomers and carbon fiber reinforced plastics based on them,” Polym. Bull., 77, No. 4, 2039-2057 (2020).CrossRef R. A. Korokhin, V. I. Solodilov, U. G. Zvereva, D. V. Solomatin, Y. A. Gorbatkina, A. V. Shapagin, and M. Y. Bamborin, “Epoxy polymers modified with polyetherimide. Part II: physicomechanical properties of modified epoxy oligomers and carbon fiber reinforced plastics based on them,” Polym. Bull., 77, No. 4, 2039-2057 (2020).CrossRef
Metadaten
Titel
Influence of Polyethersulfone on the Fracture Toughness of Epoxy Matrices and Reinforced Plastics on Their Basis
verfasst von
V. I. Solodilov
I. V. Tretyakov
T. V. Petrova
A. V. Kireynov
R. A. Korokhin
G. Y. Yurkov
Publikationsdatum
02.09.2023
Verlag
Springer US
Erschienen in
Mechanics of Composite Materials / Ausgabe 4/2023
Print ISSN: 0191-5665
Elektronische ISSN: 1573-8922
DOI
https://doi.org/10.1007/s11029-023-10128-4

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