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Journal of Materials Science: Materials in Electronics

Erschienen in:

14.07.2016

The study of structural and optical properties of PVA:PbO₂ based solid polymer nanocomposites

verfasst von: Rebar T. Abdulwahid, Omed Gh. Abdullah, Shujahadeen B. Aziz, Sarkawt A. Hussein, Fahmi F. Muhammad, Mohd Y. Yahya

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 11/2016

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Abstract

In this work the structural and optical properties of PVA:PbO₂ based solid polymer nanocomposites was investigated. The XRD results indicated the existence of both α and β phases of PbO₂ distributed along the PVA matrix. The crystallite size of PbO₂ particles was found to be in the nanoscale range (≈19 nm). A pronounced red shift in the absorption spectra and decreased energy gap of the nanocomposite films were observed upon the addition of various fractions of PbO₂. These indicated an enhancement in the intermolecular interaction between the PVA host and PbO₂ dopant. The plot of refractive index versus dopant fraction was successfully fitted to an empirical equation and a parabolic correlation was found between them, by which a homogeneous distribution of the PbO₂ nanoparticles has been confirmed. The proposed Wemple–DiDomenico model in describing the optical band gap was seen to be inconsistent, implying that the PVA:PbO₂ nanocomposite films does not obey this model. Consequently, a detailed elaboration on the optical and structural behaviours of the PVA:PbO₂ system was given.

Vorheriger Artikel Synthesis of single-phase zinc chromite nano-spinel embedded in polyvinyl alcohol films and its effects on energy band gap

Nächster Artikel Structural and optical properties of (Zn, Co) co-doped SnO2 nano particles

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Titel: The study of structural and optical properties of PVA:PbO2 based solid polymer nanocomposites
verfasst von: Rebar T. Abdulwahid
Omed Gh. Abdullah
Shujahadeen B. Aziz
Sarkawt A. Hussein
Fahmi F. Muhammad
Mohd Y. Yahya
Publikationsdatum: 14.07.2016
Verlag: Springer US
Erschienen in: Journal of Materials Science: Materials in Electronics / Ausgabe 11/2016
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-016-5363-y

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