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Cellulose

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05.06.2019 | Original Research

Towards the development of highly transparent, flexible and water-resistant bio-based nanopapers: tailoring physico-mechanical properties

verfasst von: Quim Tarrés, Pere Mutjé, Marc Delgado-Aguilar

Erschienen in: Cellulose | Ausgabe 11/2019

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Abstract

The present works aims at developing cellulose-based nanopapers from TEMPO-oxidized cellulose nanofibers with tailored properties by means of the incorporation of cheap, widely available and easy-to-use additives. For this, nanopapers were produced by means of a papermaking-like route with a modified paper sheet former. Bleached kraft eucalyptus and pine pulps (BKEP and BKPP, respectively) were selected for comparison purposes and they were submitted to three different oxidation degrees. Those nanopapers prepared from BKPP at 10 mmol/g exhibited the most well-balanced performance in terms of mechanical, optical and morphological properties and were selected for the study with glycerol and AKD. It was found that as the amount of glycerol was increased, mechanical properties were decreased due to a plasticizing effect, with no influence on water contact angle (WCA) and transmittance. However, when AKD was used, and especially when combined with glycerol, mechanical properties and WCA were significantly improved, mainly due to the esterification reaction. Overall, the present work shows different ways to tailor the mechanical, optical, surface and morphological properties of nanopapers, obtaining significant improvements on several properties with the combination of other additives, which can be easily found in cellulose-based industries.

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Vorheriger Artikel Electrospinning of photo-responsive Azo-Cellulose: towards smart fibrous materials

Nächster Artikel Localization of cellulosic fines in paper via fluorescent labeling

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Bacarin GB, Cabrera FC, Da Silva MR, Job AE (2017) The distribution of lignin and xylan in the inner and surface layers of the fiber from eucalyptus kraft pulp and its effects on oxygen delignification. Mater Res 20:945–950. https://doi.org/10.1590/1980-5373-MR-2016-0687 CrossRef

Benkaddour A, Journoux-Lapp C, Jradi K et al (2014) Study of the hydrophobization of TEMPO-oxidized cellulose gel through two routes: amidation and esterification process. J Mater Sci 49:2832–2843. https://doi.org/10.1007/s10853-013-7989-y CrossRef

Besbes I, Vilar MR, Boufi S (2011) Nanofibrillated cellulose from alfa, eucalyptus and pine fibres: preparation, characteristics and reinforcing potential. Carbohydr Polym 86:1198–1206. https://doi.org/10.1016/j.carbpol.2011.06.015 CrossRef

Bildik AE, Hubbe MA, Gurboy KB (2016) Alkyl ketene dimer (AKD) sizing of paper under simplified treatment conditions. Tappi J 15:545–552

Boufi S, Belgacem MN (2006) Modified cellulose fibres for adsorption of dissolved organic solutes. Cellulose. https://doi.org/10.1007/s10570-005-9019-y CrossRef

Bras J, Vaca-Garcia C, Borredon ME, Glasser W (2007) Oxygen and water vapor permeability of fully substituted long chain cellulose esters (LCCE). Cellulose. https://doi.org/10.1007/s10570-007-9123-2 CrossRef

Cervin NT, Aulin C, Larsson PT, Wågberg L (2012) Ultra porous nanocellulose aerogels as separation medium for mixtures of oil/water liquids. Cellulose 19:401–410. https://doi.org/10.1007/s10570-011-9629-5 CrossRef

Cui Y, Kumar S, Rao Kona B, Van Houcke D (2015) Gas barrier properties of polymer/clay nanocomposites. RSC Adv 5:63669–63690. https://doi.org/10.1039/c5ra10333a CrossRef

Cunha AG, Gandini A (2010) Turning polysaccharides into hydrophobic materials: a critical review. Part 1. Cellulose. https://doi.org/10.1007/s10570-010-9434-6 CrossRef

Cunha AG, Zhou Q, Larsson PT, Berglund LA (2014) Topochemical acetylation of cellulose nanopaper structures for biocomposites: mechanisms for reduced water vapour sorption. Cellulose. https://doi.org/10.1007/s10570-014-0334-z CrossRef

da Silva Perez D, Montanari S, Vignon MR (2003) TEMPO-mediated oxidation of cellulose III. Biomacromolecules 4:1417–1425. https://doi.org/10.1021/bm034144s CrossRefPubMed

De France KJ, Hoare T, Cranston ED (2017) Review of hydrogels and aerogels containing nanocellulose. Chem Mater 29:4609–4631. https://doi.org/10.1021/acs.chemmater.7b00531 CrossRef

Dehnad D, Emam-Djomeh Z, Mirzaei H et al (2014) Optimization of physical and mechanical properties for chitosan–nanocellulose biocomposites. Carbohydr Polym. https://doi.org/10.1016/j.carbpol.2014.01.094 CrossRefPubMed

Delgado-Aguilar M, González I, Pèlach MA et al (2015a) Improvement of deinked old newspaper/old magazine pulp suspensions by means of nanofibrillated cellulose addition. Cellulose 22:789–802. https://doi.org/10.1007/s10570-014-0473-2 CrossRef

Delgado-Aguilar M, González I, Tarrés Q et al (2015b) Approaching a low-cost production of cellulose nanofibers for papermaking applications. BioResources 10:5345–5355. https://doi.org/10.15376/biores.10.3.5330-5344 CrossRef

Dorris A, Gray DG (2012) Gelation of cellulose nanocrystal suspensions in glycerol. Cellulose 19:687–694. https://doi.org/10.1007/s10570-012-9679-3 CrossRef

Dufresne A (2013) Nanocellulose: from nature to high performance tailored materials. Walter de Gruyter, Germany

Espinosa E, Tarrés Q, Delgado-Aguilar M et al (2016) Suitability of wheat straw semichemical pulp for the fabrication of lignocellulosic nanofibres and their application to papermaking slurries. Cellulose 23:837–852. https://doi.org/10.1007/s10570-015-0807-8 CrossRef

EU Commission (2018) Proposal for a directive of the European Parliament and of the Council on the reduction of the impact of certain plastic products on the environment. 2018/0172:33. COM(2018) 340 final 2018/0172 (COD)

Fujisawa S, Okita Y, Fukuzumi H et al (2011) Preparation and characterization of TEMPO-oxidized cellulose nanofibril films with free carboxyl groups. Carbohydr Polym 84:579–583. https://doi.org/10.1016/j.carbpol.2010.12.029 CrossRef

González I, Alcalà M, Chinga-Carrasco G et al (2014) From paper to nanopaper: evolution of mechanical and physical properties. Cellulose 21:2599–2609. https://doi.org/10.1007/s10570-014-0341-0 CrossRef

Grüneberger F, Künniger T, Zimmermann T, Arnold M (2014) Rheology of nanofibrillated cellulose/acrylate systems for coating applications. Cellulose 21:1313–1326. https://doi.org/10.1007/s10570-014-0248-9 CrossRef

Guo G, Zhang C, Du Z et al (2015) Processing and properties of phthalic anhydride modified soy protein/glycerol plasticized soy protein composite films. J Appl Polym Sci 132:2–7. https://doi.org/10.1002/app.42221 CrossRef

Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals : chemistry, self-assembly, and applications. Chem Rev. https://doi.org/10.1021/cr900339w CrossRefPubMed

Hansson JA, Hartler N (1969) Sorption of hemicelluloses on cellulose fibres. Sorption of xylans. Sven Papperstidn 72:521–530

Henriksson M, Henriksson G, Berglund LA, Lindström T (2007) An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers. Eur Polym J 43:3434–3441. https://doi.org/10.1016/j.eurpolymj.2007.05.038 CrossRef

Hoeng F, Denneulin A, Bras J (2016) Use of nanocellulose in printed electronics: a review. Nanoscale 8:13131–13154. https://doi.org/10.1039/c6nr03054h CrossRefPubMed

Hubbe MA (2014) Prospects for maintaining strength of paper and paperboard products while using less forest resources: a review. BioResources 9:1634–1763

Hundhausen U, Militz H, Mai C (2009) Die Verwendung von Alkylketendimer (AKD) zur oberflächenmodifizierung von Spänen für die Herstellung von Spanplatten. Eur J Wood Wood Prod 67:37–45. https://doi.org/10.1007/s00107-008-0275-z CrossRef

Isogai A, Saito T, Fukuzumi H (2011) TEMPO-oxidized cellulose nanofibers. Nanoscale 3:71–85. https://doi.org/10.1039/c0nr00583e CrossRefPubMed

Kiziltas EE, Kiziltas A, Nazari B et al (2016) Glycerine treated nanofibrillated cellulose composites. J Nanomater 2016:18–25. https://doi.org/10.1155/2016/7851308 CrossRef

Lee SH, Shiraishi N (2001) Plasticization of cellulose diacetate by reaction with maleic anhydride, glycerol, and citrate esters during melt processing. J Appl Polym Sci. https://doi.org/10.1002/app.1435 CrossRef

Li Q, McGinnis S, Sydnor C et al (2013) Nanocellulose life cycle assessment. ACS Sustain Chem Eng 1:919–928. https://doi.org/10.1021/sc4000225 CrossRef

Lizundia E, Delgado-Aguilar M, Mutjé P et al (2016) Cu-coated cellulose nanopaper for green and low-cost electronics. Cellulose 23:1997–2010. https://doi.org/10.1007/s10570-016-0920-3 CrossRef

Mahfoudhi N, Boufi S (2017) Nanocellulose as a novel nanostructured adsorbent for environmental remediation: a review. Cellulose 24:1171–1197CrossRef

Mende H, Olenik D, Schleppers A (2016) G-DRG-Version 2016 - Auswirkungen auf unser Fachgebiet. Anasthesiol und Intensivmed 57:147–151. https://doi.org/10.1002/pen CrossRef

Naderi A, Lindström T (2014) Carboxymethylated nanofibrillated cellulose: effect of monovalent electrolytes on the rheological properties. Cellulose 21:3507–3514. https://doi.org/10.1007/s10570-014-0394-0 CrossRef

Nelson K, Retsina T, Iakovlev M et al (2016) American process: production of low cost nanocellulose for renewable, advanced materials applications. In: Madsen LD, Svedberg EB (eds) Materials research for manufacturing. Springer, Berlin, pp 267–302CrossRef

Nemet NT, Šošo VM, Lazić VL (2010) Effect of glycerol content and pH value of film-forming solution on the functional properties of protein-based edible films. Acta Period Technol 41:57–67. https://doi.org/10.2298/APT1041057N CrossRef

Nogi M, Komoda N, Otsuka K, Suganuma K (2013) Foldable nanopaper antennas for origami electronics. Nanoscale 5:4395–4399. https://doi.org/10.1039/c3nr00231d CrossRefPubMed

Osong SH, Norgren S, Engstrand P (2016) Processing of wood-based microfibrillated cellulose and nanofibrillated cellulose, and applications relating to papermaking: a review. Cellulose 23:93–123. https://doi.org/10.1007/s10570-015-0798-5 CrossRef

Pääkkönen T, Dimic-Misic K, Orelma H et al (2016) Effect of xylan in hardwood pulp on the reaction rate of TEMPO-mediated oxidation and the rheology of the final nanofibrillated cellulose gel. Cellulose 23:277–293. https://doi.org/10.1007/s10570-015-0824-7 CrossRef

Peng BL, Dhar N, Liu HL, Tam KC (2011) Chemistry and applications of nanocrystalline cellulose and its derivatives: a nanotechnology perspective. Can J Chem Eng 89:1191–1206. https://doi.org/10.1002/cjce.20554 CrossRef

Rhim JW, Hong SI, Ha CS (2009) Tensile, water vapor barrier and antimicrobial properties of PLA/nanoclay composite films. LWT Food Sci Technol 42:612–617. https://doi.org/10.1016/j.lwt.2008.02.015 CrossRef

Saito T, Kimura S, Nishiyama Y, Isogai A (2007) Cellulose nanofibers prepared by TEMPO-mediated oxidation of native cellulose. Biomacromolecules 8:2485–2491. https://doi.org/10.1021/bm0703970 CrossRefPubMed

Sehaqui H, Liu A, Zhou Q, Berglund LA (2010) Fast preparation procedure for large, flat cellulose and cellulose/inorganic nanopaper structures. Biomacromolecules. https://doi.org/10.1021/bm100490s CrossRefPubMed

Sehaqui H, Zhou Q, Berglund LA (2011) Nanostructured biocomposites of high toughness—a wood cellulose nanofiber network in ductile hydroxyethylcellulose matrix. Soft Matter 7:7342. https://doi.org/10.1039/c1sm05325f CrossRef

Sehaqui H, Mautner A, Perez De Larraya U et al (2016) Cationic cellulose nanofibers from waste pulp residues and their nitrate, fluoride, sulphate and phosphate adsorption properties. Carbohydr Polym 135:334–340. https://doi.org/10.1016/j.carbpol.2015.08.091 CrossRefPubMed

Serra A, González I, Oliver-Ortega H et al (2017) Reducing the amount of catalyst in TEMPO-oxidized cellulose nanofibers: effect on properties and cost. Polymers (Basel). https://doi.org/10.3390/polym9110557 CrossRef

Shinoda R, Saito T, Okita Y, Isogai A (2012) Relationship between length and degree of polymerization of TEMPO-oxidized cellulose nanofibrils. Biomacromolecules 13:842–849CrossRefPubMed

Syverud K, Chinga-Carrasco G, Toledo J, Toledo PG (2011) A comparative study of Eucalyptus and Pinus radiata pulp fibres as raw materials for production of cellulose nanofibrils. Carbohydr Polym 84:1033–1038. https://doi.org/10.1016/j.carbpol.2010.12.066 CrossRef

Tarrés Q, Oliver-Ortega H, Llop M et al (2016a) Effective and simple methodology to produce nanocellulose-based aerogels for selective oil removal. Cellulose 23:3077–3088. https://doi.org/10.1007/s10570-016-1017-8 CrossRef

Tarrés Q, Saguer E, Pèlach MA et al (2016b) The feasibility of incorporating cellulose micro/nanofibers in papermaking processes: the relevance of enzymatic hydrolysis. Cellulose 23:1433–1445. https://doi.org/10.1007/s10570-016-0889-y CrossRef

Tarrés Q, Boufi S, Mutjé P, Delgado-Aguilar M (2017) Enzymatically hydrolyzed and TEMPO-oxidized cellulose nanofibers for the production of nanopapers: morphological, optical, thermal and mechanical properties. Cellulose. https://doi.org/10.1007/s10570-017-1394-7 CrossRef

Tarrés Q, Oliver-Ortega H, Ferreira PJ et al (2018) Towards a new generation of functional fiber-based packaging: cellulose nanofibers for improved barrier, mechanical and surface properties. Cellulose 25:683–695. https://doi.org/10.1007/s10570-017-1572-7 CrossRef

Theng D, Arbat G, Delgado-Aguilar M et al (2015) All-lignocellulosic fiberboard from corn biomass and cellulose nanofibers. Ind Crops Prod 76:166–173. https://doi.org/10.1016/j.indcrop.2015.06.046 CrossRef

Vieira MGA, Da Silva MA, Dos Santos LO, Beppu MM (2011) Natural-based plasticizers and biopolymer films: a review. Eur Polym J 47:254–263. https://doi.org/10.1016/j.eurpolymj.2010.12.011 CrossRef

Wei H, Rodriguez K, Renneckar S, Vikesland PJ (2014) Environmental science and engineering applications of nanocellulose-based nanocomposites. Environ Sci Nano 1:302–316. https://doi.org/10.1039/c4en00059e CrossRef

Wellisch E, Hagan L, Marker L, Sweeting OJ (1960) Interaction of cellulose with small molecules. Glycerol and ethylene carbonate. J Appl Polym Sci. https://doi.org/10.1002/app.1960.070030910 CrossRef

Yang Q, Saito T, Isogai A (2012) Facile fabrication of transparent cellulose films with high water repellency and gas barrier properties. Cellulose 19:1913–1921. https://doi.org/10.1007/s10570-012-9790-5 CrossRef

Zhu H, Narakathu BB, Fang Z et al (2014) A gravure printed antenna on shape-stable transparent nanopaper. Nanoscale 6:9110–9115. https://doi.org/10.1039/c4nr02036g CrossRefPubMed

Titel: Towards the development of highly transparent, flexible and water-resistant bio-based nanopapers: tailoring physico-mechanical properties
verfasst von: Quim Tarrés
Pere Mutjé
Marc Delgado-Aguilar
Publikationsdatum: 05.06.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 11/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02524-8

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