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01.02.2017 | Research Paper

In situ surface-enhanced Raman spectroscopy effect in zeolite due to Ag₂Se quantum dots

verfasst von: C. E. Martinez-Nuñez, M. Cortez-Valadez, Y. Delgado-Beleño, N. S. Flores-López, J. F. Román-Zamorano, J. Flores-Valenzuela, M. Flores-Acosta

Erschienen in: Journal of Nanoparticle Research | Ausgabe 2/2017

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Abstract

This study shows the presence of surface-enhanced Raman spectroscopy (SERS) effect caused by Ag₂Se quantum dots embedded in the zeolite matrix. The quantum dots that were synthesised and stabilised in the matrix of F9-NaX zeolite show a size of 5 nm and a quasi-spherical morphology. The calculated interplanar distances confirm the presence of quantum dots in cubic phase Im-m. We suppose that the in situ SERS effect in the material is caused by chemical-enhancement mechanism (CEM). The density functional theory (DFT) is undertaken to corroborate our hypothesis. The structure H₈Si₈Al₈O₁₂ represents the zeolite cavity unit, and small clusters of (Ag₂Se)_n represent the quantum dots. Both structures interact in the cavity to obtain the local minimum of the potential energy surface, leading to new molecular orbitals. After the analysis of the predicted Raman spectrum, the Raman bands increase significantly, agreeing with the experimental results at low wavenumbers in F9-NaX zeolite.

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Nächster Artikel Transformation from Ag@Ag3PO4 to Ag@Ag2SO4 hybrid at room temperature: preparation and its visible light photocatalytic activity

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Titel: In situ surface-enhanced Raman spectroscopy effect in zeolite due to Ag2Se quantum dots
verfasst von: C. E. Martinez-Nuñez
M. Cortez-Valadez
Y. Delgado-Beleño
N. S. Flores-López
J. F. Román-Zamorano
J. Flores-Valenzuela
M. Flores-Acosta
Publikationsdatum: 01.02.2017
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 2/2017
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-016-3725-2

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