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Biomass Conversion and Biorefinery
Erschienen in: Biomass Conversion and Biorefinery 2/2019

04.12.2018 | Original Article

Efficient metal-free conversion of glucose to 5-hydroxymethylfurfural using a boronic acid

verfasst von: Brian J. Graham, Ronald T. Raines

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 2/2019

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Abstract

5-Hydroxymethylfurfural (HMF), which can be synthesized from hexose sugars without rearrangement of their carbon framework, is a key platform chemical that is readily convertible into fuels and chemicals that are now derived from petroleum. Methods to convert glucose, which is readily accessible from cellulose, to HMF typically rely on toxic heavy metals or harsh acidic conditions and often give low yields or low selectivity. Here, we report on a mild, efficient, and metal-free process that uses an organocatalyst, 2-carboxyphenylboronic acid, along with small amounts of chloride ion to effect the selective transformation of glucose to HMF.
Vorheriger Artikel Characterization of products obtained from hydrothermal liquefaction of biomass (Anchusa azurea) compared to other thermochemical conversion methods

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Metadaten
Titel
Efficient metal-free conversion of glucose to 5-hydroxymethylfurfural using a boronic acid
verfasst von
Brian J. Graham
Ronald T. Raines
Publikationsdatum
04.12.2018
Verlag
Springer Berlin Heidelberg
Erschienen in
Biomass Conversion and Biorefinery / Ausgabe 2/2019
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI
https://doi.org/10.1007/s13399-018-0346-2

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