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Polymer Bulletin
Erschienen in: Polymer Bulletin 1/2019

07.06.2018 | Original Paper

Synthesis and characterization of poly(ester amide amide)s of different alkylene chain lengths

verfasst von: Clément Girard, Manisha Gupta, Abdelaziz Lallam, Denis V. Anokhin, Polina V. Bovsunovskaya, Azaliya F. Akhyamova, Alexey P. Melnikov, Alexey A. Piryazev, Alexander I. Rodygin, Andrey A. Rychkov, Kseniia N. Grafskaya, Ekaterina D. Shabratova, Xiaomin Zhu, Martin Möller, Dimitri A. Ivanov

Erschienen in: Polymer Bulletin | Ausgabe 1/2019

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Abstract

In this work, a series of aliphatic biodegradable poly(ester amide amide) polymers was synthesized by melt polycondensation of a tailor-made amide-containing monomer based on 1,4-diaminobutane and ε-caprolactone and different dicarboxylic acid methyl esters with even number of methylene groups. The synthesized polymers were characterized by 1H NMR, FT-IR spectroscopy, GPC, SAXS and WAXS. DSC results show that the melting point is located at about 150 °C for all polymers. X-ray scattering experiments in small and wide angles reveal formation of crystals with extended-chain conformation resulting in strict periodicity of electron density along the main chain. TGA data indicate the high thermal stability of polymers to temperatures above 350 °C, which are much above the melting point. The obtained characteristics of the newly synthesized PEAAs can open new perspectives for melt processing to fabricate films, highly oriented fibers and injection-molded parts with good thermal stability and mechanical performance.
Vorheriger Artikel An escalation of anticorrosion and microelectrical properties of polyurethane nanocomposites from green Brassica nigra oil
Nächster Artikel Thermomechanical behaviour of zirconia–multiwalled carbon nanotube-reinforced polypropylene hybrid composites

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Metadaten
Titel
Synthesis and characterization of poly(ester amide amide)s of different alkylene chain lengths
verfasst von
Clément Girard
Manisha Gupta
Abdelaziz Lallam
Denis V. Anokhin
Polina V. Bovsunovskaya
Azaliya F. Akhyamova
Alexey P. Melnikov
Alexey A. Piryazev
Alexander I. Rodygin
Andrey A. Rychkov
Kseniia N. Grafskaya
Ekaterina D. Shabratova
Xiaomin Zhu
Martin Möller
Dimitri A. Ivanov
Publikationsdatum
07.06.2018
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 1/2019
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-018-2361-7

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