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Journal of Materials Engineering and Performance
Erschienen in: Journal of Materials Engineering and Performance 5/2017

18.04.2017

Synthesis, Characterization and Electrochemical Behavior of Al/Yb/Co/Mn-Doped α-Ni(OH)2

verfasst von: Xiuwen Jian, Yanjuan Zhu, Wenhua Li, Tengqi Zhao

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 5/2017

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Abstract

Multi-element-doped α-Ni(OH)2 was prepared by an ultrasonic-assisted co-precipitation method. The crystal structures and morphologies of the prepared samples were characterized by x-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy, respectively. The results showed that the interlayer spacings of all samples were larger than that of pure α-Ni(OH)2 and that the structural stability became better with increases in the number of doped elements and the doped ratio. The electrochemical performances of the prepared samples, including cyclic voltammetry, electrochemical impedance spectroscopy and charge-discharge tests, were also analyzed. The results indicated that Al/Yb/Co/Mn-doped α-Ni(OH)2 had better electrochemical reversibility, lower charge-transfer resistance, a larger proton diffusion coefficient (8.47 × 10−12 cm−2/s) and a higher discharge capacity (288.2 mAh g−1 at 0.5 °C) than Al/Co/Mn-doped α-Ni(OH)2 due to the synergistic effect of the doped elements.
Vorheriger Artikel The Effect of Ca Content on the Microstructure, Hardness and Tensile Properties of AZ81 Mg Cast Alloy
Nächster Artikel Constitutive Modeling of Warm Deformation Flow Curves of an Eutectoid Steel

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Metadaten
Titel
Synthesis, Characterization and Electrochemical Behavior of Al/Yb/Co/Mn-Doped α-Ni(OH)2
verfasst von
Xiuwen Jian
Yanjuan Zhu
Wenhua Li
Tengqi Zhao
Publikationsdatum
18.04.2017
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 5/2017
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-017-2682-y

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