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Polymer Bulletin

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06.10.2022 | Original Paper

Tailoring structural, optical characteristics of CuO/In₂O₃ nanoparticles-doped organic material for photodegradation of dyes pollutants

verfasst von: Huda Bukheet Hassan, Ahmed Hashim, Hayder M. Abduljalil

Erschienen in: Polymer Bulletin | Ausgabe 8/2023

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Abstract

In present work, nanocomposites films of polyethylene oxide (PEO), copper oxide (CuO) nanoparticles and indium oxide (In₂O₃) nanoparticles have been fabricated for discoloration and photo-degradation of dyes pollutants with high efficiency, few cost, anti-aggregation and high dispersion of nanoparticles. The structural and optical properties of PEO/CuO–In₂O₃ nanocomposites have been investigated. The structural properties were included the tests: optical microscopic (OM), scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FTIR). The optical properties of PEO/CuO–In₂O₃ nanocomposites were studied in wavelength range (200–800) nm. The results of optical properties of PEO/CuO–In₂O₃ nanocomposites showed the absorbance of PEO increases about 57.4% at (λ = 500 nm) and the energy gap of PEO reduces about 41.1% with adding of CuO–In₂O₃NPs which may be considered as a key for various optical and electronic fields. The optical constant of PEO were improved by adding of CuO NPs and CuO–In₂O₃ NPs. The PEO/CuO–In₂O₃ nanocomposites have been utilized for photo-degradation of dyes pollutants. The results showed prepared nanocomposites can be used for excellent photo-degradation of dyes with high efficiency reached 91% and low concentration of nanoparticles.

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Rahman MT et al (2019) Study on the mechanical, electrical and optical properties of metal-oxide nanoparticles dispersed unsaturated polyester resin nanocomposites. Results Phys 13:102264CrossRef

Abutalib MM, Rajeh A (2020) Influence of MWCNTs/Li-doped TiO2 nanoparticles on the structural, thermal, electrical and mechanical properties of poly (ethylene oxide)/poly (methylmethacrylate) composite. J Organomet Chem 918:121309CrossRef

Sundaramahalingam K, Vanitha D, Nallamuthu N, Manikandan A, Muthuvinayagam M (2019) Electrical properties of lithium bromide poly ethylene oxide/poly vinyl pyrrolidone polymer blend elctrolyte. Phys B Condens Matter 553:120–126CrossRef

Kumar KK, Ravi M, Pavani Y, Bhavani S, Sharma AK, Narasimha Rao VVR (2014) Investigations on PEO/PVP/NaBrcomplexed polymer blend electrolytes for electrochemical cell applications. J Membr Sci 454:200–211CrossRef

Kumar KK, Ravi M, Pavani Y, Bhavani S, Sharma AK, Narasimha Rao VVR (2012) Electrical conduction mechanism in NaCl complexed PEO/PVP polymer blend electrolytes. J Non-Cryst Solids 358(23):3205–3211CrossRef

Menazea AA (2020) One-Pot Pulsed Laser Ablation route assisted copper oxide nanoparticles doped in PEO/PVP blend for the electrical conductivity enhancement. J Market Res 9(2):2412–2422

Morsi MA, Rajeh A, Al-Muntaser AA (2019) Reinforcement of the optical, thermal and electrical properties of PEO based on MWCNTs/Au hybrid fillers: nanodielectric materials for organoelectronic devices. Compos B Eng 173:106957CrossRef

Spěváček J, Brus J, Dybal J (2005) Solid state NMR and DFT study of polymer electrolyte poly(ethylene oxide)/LiCF3SO3. Solid State Ion 176(1–2):163–167CrossRef

Wang S-B, Hsiao C-H, Chang S-J, Lam K-T, Wen K-H, Young S-J, Hung S-C, Huang B-R (2011) CuO nanowire-based humidity sensor. IEEE Sens J 12(6):1884–1888CrossRef

10.

Verma M, Kumar V, Katoch A (2018) Sputtering based synthesis of CuO nanoparticles and their structural, thermal and optical studies. Mater Sci Semicond Process 76:55–60CrossRef

11.

Rasheed RT (2017) Theoretical structures study of indium oxide (In₂O₃) cluster using DFT calculations. Asian J Mater Chem 2(1):26–29CrossRef

12.

Yang H, Wang S, Yang Y (2012) Zn-doped In2O3 nanostructures: preparation, structure and gas-sensing properties. CrystEngComm 14(3):1135–1142CrossRef

13.

Zhanpeisov NU, Nakatani H, Fukumura H (2011) Theoretical DFT study of the structure and chemical activity of small indium (III) oxide clusters. Res Chem Intermed 37(6):647–658CrossRef

14.

Jothibas M, Manoharan C, Johnson Jeyakumar S, Praveen P (2015) Study on structural and optical behaviors of In₂O₃ nanocrystals as potential candidate for optoelectronic devices. J Mater Sci Mater Electron 26:9600–9606. https://doi.org/10.1007/s10854-015-3623-xCrossRef

15.

Henaish AMA, Abouhaswa AS (2020) Effect ofWO3 nanoparticle doping on the physical properties of PVC polymer. Bull Mater Sci. https://doi.org/10.1007/s12034-020-2109-5CrossRef

16.

Mahalakshmi K, Lakshmi V, Anitha SDC, MaryJenila R (2021) Optical, structural and morphological analysis of rGO decorated CoSe2 nanocomposites. Int J Innov Sci Eng Technol 8(2):180–192

17.

Salman S, Abduallah M, Bakr N (2014) Optical characterization of red methyl doped poly (vinyl alcohol) films. Int J Eng Technol Res 2(4):126–128

18.

Tyagi C, Devi A (2018) Alteration of structural, optical and electrical properties of CdSe incorporated polyvinyl pyrrolidone nanocomposite for memory devices. J Adv Dielectr. https://doi.org/10.1142/S2010135X18500200CrossRef

19.

Chiladova A, Wiener J, Polakova M (2011) Testing the phoyocatalytic activity of TiO2 nanoparticles with potassium permanganate solution. NanoConTM 21:9

20.

Al-Shamari AA et al (2021) Structural and optical properties of PEO/CMC polymer blend modified with gold nanoparticles synthesized by laser ablation in water. J Market Res 12:1597–1605

21.

Ahmad W, Jabbar B, Ahmad I, Jan BM, Stylianakis MM, Kenanakis G, Ikram R (2021) Highly sensitive humidity sensors based on polyethylene oxide/CuO/multi walled carbon nanotubes composite nanofibers. Materials 14(4):1037CrossRefPubMedPubMedCentral

22.

Mansor ES, Ali H, Abdel-Karim A (2020) Efficient and reusable polyethylene oxide/polyaniline composite membrane for dye adsorption and filtration. Colloid Interface Sci Commun 39:100314CrossRef

23.

Menazea AA, Ahmed MK (2020) Nanosecond laser ablation assisted the enhancement of antibacterial activity of copper oxide nano particles embedded though polyethylene oxide/polyvinyl pyrrolidone blend matrix. Radiat Phys Chem 174:108911CrossRef

24.

Hadi A, Hashim A, Al-Khafaji Y (2020) Structural, optical and electrical properties of PVA/PEO/SnO₂ new nanocomposites for flexible devices. Trans Electr Electron Mater 21:283–292. https://doi.org/10.1007/s42341-020-00189-wCrossRef

25.

Abutalib MM, Rajeh A (2021) Enhanced structural, electrical, mechanical properties and antibacterial activity of Cs/PEO doped mixed nanoparticles (Ag/TiO₂) for food packaging applications. Polym Testing 93:107013CrossRef

26.

Hashim A, H MAbduljalil, H Ahmed, (2020) Fabrication and characterization of (PVA-TiO2)1–x/SiCx nanocomposites for biomedical applications. Egypt J Chem. https://doi.org/10.21608/EJCHEM.2019.10712.1695CrossRef

27.

Abduljalil H, Hashim A, Jewad A (2011) The effect of addition titanium dioxide on electrical properties of poly-methyl methacrylate. Eur J Sci Res 63(2):231

28.

Hashim A (2021) Synthesis of SiO₂/CoFe₂O₄ nanoparticles doped CMC: exploring the morphology and optical characteristics for photodegradation of organic dyes. J Inorg Organomet Polym Mater 31:2483. https://doi.org/10.1007/s10904-020-01846-6CrossRef

29.

Hashim A (2021) Fabrication and characteristics of flexible, lightweight, and low-cost pressure sensors based on PVA/SiO₂/SiC nanostructures. J Mater Sci Mater Electron 32:2796. https://doi.org/10.1007/s10854-020-05032-9CrossRef

30.

Al-Ramadhan Z, Algidsawi AJK, Hashim A (2011) The DC electrical properties of (PVC-Al₂O₃) composites. AIP Conf Proc 1400(1):180–185. https://doi.org/10.1063/1.3663109CrossRef

31.

Hashim A, Hadi Q (2017) Novel of (niobium carbide/polymer blend) nanocomposites: fabrication and characterization for pressure sensors. Sens Lett 15(11):951. https://doi.org/10.1166/sl.2017.3892CrossRef

32.

DeMerlis CC, Schoneker DR (2003) Review of the oral toxicity of polyvinyl alcohol (PVA). Food Chem Toxicol 41(3):319–326CrossRefPubMed

33.

Rashid FL, Hashim A, Habeeb MA, Salman SR, Ahmed H (2013) Preparation of PS-PMMA copolymer and study the effect of sodium fluoride on its optical properties. J Eng Appl Sci 8(5):137–139

34.

Hadi A, Hashim A (2017) Development of a new humidity sensor based on (carboxymethyl cellulose–starch) blend with copper oxide nanoparticles. Ukr J Phys. https://doi.org/10.15407/ujpe62.12.1044CrossRef

35.

Ahmed H, Hashim A, Abduljalil HM (2020) Determination of optical parameters of films of PVA/TiO2/SiC and PVA/MgO/SiC nanocomposites for optoelectronics and UV-detectors. Ukr J Phys. https://doi.org/10.15407/ujpe65.6.533CrossRef

36.

Hashim A (2021) Enhanced morphological, optical and electronic characteristics of WC NPs doped PVP/PEO for flexible and lightweight optoelectronics applications. Opt Quant Electron 53:478. https://doi.org/10.1007/s11082-021-03100-wCrossRef

37.

Phukan P, Saikia D (2013) Optical and structural investigation of CdSe quantum dots dispersed in PVA matrix and photovoltaic applications. Int J Photoenergy. https://doi.org/10.1155/2013/728280CrossRef

38.

Hashim A, Hamad ZS (2019) Fabrication and characterization of polymer blend doped with metal carbide nanoparticles for humidity sensors. J Nanostruct 9(2):340–348. https://doi.org/10.22052/JNS.2019.02.016CrossRef

39.

Hashim A, Jassim A (2017) Novel of (PVA-ST-PbO₂) Bio nanocomposites: preparation and properties for humidity sensors and radiation shielding applications. Sens Lett. https://doi.org/10.1166/sl.2018.3915CrossRef

40.

Indolia A, Gaur M (2013) Optical properties of solution grown PVDF–ZnOnanocomposite thin films. J Polym Res 20:43–50CrossRef

41.

Ahmed H, Hashim A (2020) Lightweight, flexible and high energies absorption property of PbO₂ doped polymer blend for various renewable approaches. Trans Electr Electron Mater. https://doi.org/10.1007/s42341-020-00244-6CrossRef

42.

Hazim A, Abduljalil HM, Hashim A (2020) Structural, spectroscopic, electronic and optical properties of novel platinum doped (PMMA/ZrO₂) and (PMMA/Al₂O₃) nanocomposites for electronics devices. Trans Electr Electron Mater. https://doi.org/10.1007/s42341-020-00210-2CrossRef

43.

Alghunaim NS (2015) Spectroscopic analysis of PMMA/PVC blends containing CoCl₂. Results in Phys. https://doi.org/10.1016/j.rinp.2015.11.003CrossRef

44.

Hashim A (2020) Enhanced structural, optical, and electronic properties of In₂O₃ and Cr₂O₃ nanoparticles doped polymer blend for flexible electronics and potential applications. J Inorg Organomet Polym 30:3894–3906. https://doi.org/10.1007/s10904-020-01528-3CrossRef

45.

Hazim A, Hashim A, Abduljalil HM (2019) Analysis of structural and electronic, properties of novel (PMMA/Al₂O₃, PMMA/Al₂O₃-Ag, PMMA/ZrO₂-Ag, PMMA-Ag) nanocomposites for low cost electronics and optics applications. Trans Electr Electron Mater. https://doi.org/10.1007/s42341-019-00148-0CrossRef

46.

Hazim A, Abduljalil HM, Hashim A (2021) Design of PMMA doped with inorganic materials as promising structures for optoelectronics applications. Trans Electr Electron Mater 22:851–868. https://doi.org/10.1007/s42341-021-00308-1CrossRef

47.

Hazim A, Abduljalil HM, Hashim A (2020) First principles calculations of electronic, structural and optical properties of (PMMA–ZrO₂–Au) and (PMMA–Al₂O₃–Au) nanocomposites for optoelectronics applications. Trans Electr Electron Mater. https://doi.org/10.1007/s42341-020-00224-wCrossRef

48.

Laila H (2020) Gaabour, analysis of spectroscopic, optical and magnetic behaviour of PVDF/PMMA blend embedded by magnetite (Fe₃O₄) nanoparticles. Opt Photonics J 10:197–209. https://doi.org/10.4236/opj.2020.108021CrossRef

49.

Francis P, Patil S, Rajesh C et al (2013) Electronic and optical properties of agglomerated hydrogen terminated silicon nanoparticles. Eur Phys J D 67:144. https://doi.org/10.1140/epjd/e2013-40052-3CrossRef

50.

Attia G, Abd El-Kader MFH (2013) Structural, optical and thermal characterization of PVA/2HEC polyblendfilms. Int J Electrochem Sci 8:5672–5687CrossRef

51.

Al-Aaraji NA-H, Hashim A, Hadi A, Abduljalil HM (2022) Synthesis and enhanced optical characteristics of silicon carbide/copper oxide nanostructures doped transparent polymer for optics and photonics nanodevices. SILICON. https://doi.org/10.1007/s12633-022-01730-7CrossRef

52.

Mathai CJ, Saravanan S, Anantharaman MR, Venkitachalam S, Jayalekshmi S (2002) Effect of iodine doping on the band gap of plasma polymerized aniline thin films. J Phys D Appl Phys 35(17):2206CrossRef

53.

Hashim A, Hamad ZS (2020) Lower cost and higher UV-absorption of polyvinyl alcohol/silica nanocomposites for potential applications. Egypt J Chem. https://doi.org/10.21608/EJCHEM.2019.7264.1593CrossRef

54.

Hadi S, Hashim A, Jewad A (2011) Optical properties of (PVA-LiF) composites. Aust J Basic Appl Sci 5(9):2192–2195

55.

Hassan D, Hashim A (2018) Structural and optical properties of (polystyrene-copper oxide) nanocomposites for biological applications. J Bionanosci. https://doi.org/10.1166/jbns.2018.1533CrossRef

56.

Ahmad A, Awatif A, Abdul-Majied Z (2007) Doppingefect on optical constants of polymethylmethacrylate (PMMA). J Eng Technol 25(4):558–568

Titel: Tailoring structural, optical characteristics of CuO/In2O3 nanoparticles-doped organic material for photodegradation of dyes pollutants
verfasst von: Huda Bukheet Hassan
Ahmed Hashim
Hayder M. Abduljalil
Publikationsdatum: 06.10.2022
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 8/2023
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-022-04502-w

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