Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Rare Metals
Erschienen in: Rare Metals 5/2022

19.01.2022 | Original Article

Delicate synthesis of quasi-inverse opal structural Na3V2(PO4)3/N-C and Na4MnV(PO4)3/N-C as cathode for high-rate sodium-ion batteries

verfasst von: Xin-Ran Qi, Yuan Liu, Lin-Lin Ma, Bao-Xiu Hou, Hong-Wei Zhang, Xiao-Hui Li, Ya-Shi Wang, Yi-Qing Hui, Ruo-Xun Wang, Chong-Yang Bai, Hao Liu, Jian-Jun Song, Xiao-Xian Zhao

Erschienen in: Rare Metals | Ausgabe 5/2022

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Poor conductivity and sluggish Na+ diffusion kinetic are two major drawbacks for practical application of sodium super-ionic conductor (NASICON) in sodium-ion batteries. In this work, we report a simple approach to synthesize quasi-inverse opal structural NASICON/N-doped carbon for the first time by a delicate one-pot solution-freeze drying-calcination process, aiming at fostering the overall electrochemical performance. Especially, the quasi-inverse opal structural Na3V2(PO4)3/N-C (Q-NVP/N-C) displayed continuous pores, which provides interconnected channels for electrolyte permeation and abundant contacting interfaces between electrolyte and materials, resulting in faster kinetics of redox reaction and higher proportion of capacitive behavior. As a cathode material for sodium-ion batteries, the Q-NVP/N-C exhibits high specific capacity of 115 mAh·g−1 at 1C, still 61 mAh·g−1 at ultra-high current density of 100C, and a specific capacity of 89.7 mAh·g−1 after 2000 cycles at 20C. This work displays the general validity of preparation method for not only Q-NVP/N-C, but also Na4MnV(PO4)3, which provides a prospect for delicate synthesis of NASICON materials with excellent electrochemical performance.

Graphical Abstract

Vorheriger Artikel Rational construction of densely packed Si/MXene composite microspheres enables favorable sodium storage
Nächster Artikel Improvement of cycle behavior of Si/Sn anode composite supported by stable Si–O–C skeleton

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
[1]
Yang J, Wan HL, Zhang ZH, Liu GZ, Xu XX, Hu YS, Yao XY. NASICON-structured Na3.1Zr1.95Mg0.05Si2PO12 solid electrolyte for solid-state sodium batteries. Rare Met. 2018;37(6):480.
[2]
Zeng X, Peng J, Guo Y, Zhu H, Huang X. Research progress on Na3V2(PO4)3 cathode material of sodium ion battery. Front Chem. 2020;8:635.
[3]
Bao S, Huang YY, Luo SH, Lu JL. Porous Na3V2(PO4)3/C as cathode material for high-rate sodium-ion batteries by sacrificed template method. Ionics. 2020;26(10):5011.
[4]
[5]
Hu F, Jiang X. A stable and superior performance of Na3V2(PO4)3/C nanocomposites as cathode for sodium-ion batteries. Inorg Chem Commun. 2020;115:107860.
[6]
Hou B, Ma L, Zang X, Shang N, Song J, Zhao X, Wang C, Qi J, Wang J, Yu R. Design and construction of 3D porous Na3V2(PO4)3/C as high performance cathode for sodium ion batteries. Chem Res Chin Univ. 2021;37:265.
[7]
Cheng J, Chen Y, Sun S, Tian Z, Linghu Y, Tian Z, Wang C, He Z, Guo L. Na3V2(PO4)3/C·Na3V2(PO4)2F3/C@rGO blended cathode material with elevated energy density for sodium ion batteries. Ceram Int. 2021;47(13):18065.
[8]
[9]
Li H, Bi X, Bai Y, Yuan Y, Shahbazian-Yassar R, Wu C, Wu F, Lu J, Amine K. High-rate, durable sodium-ion battery cathode enabled by carbon-coated micro-sized Na3V2(PO4)3 particles with interconnected vertical nanowalls. Adv Mater Interfaces. 2016;3(9):1500740.
[10]
Ren H, Yu R, Qi J, Zhang L, Jin Q, Wang D. Hollow multishelled heterostructured anatase/TiO2 (B) with superior rate capability and cycling performance. Adv Mater. 2019;31(10):1805754.
[11]
Bi R, Mao D, Wang J, Yu R, Wang D. Hollow nanostructures for surface/interface chemical energy storage application. Acta Chim Sin. 2020;78(11):1200.
[12]
Zhao X, Wang J, Yu R, Wang D. Construction of multishelled binary metal oxides via coabsorption of positive and negative ions as a superior cathode for sodium-ion batteries. J Am Chem Soc. 2018;140(49):17114.
[13]
Li S, He W, Liu B, Cui J, Wang X, Peng DL, Liu B, Qu B. One-step construction of three-dimensional nickel sulfide-embedded carbon matrix for sodium-ion batteries and hybrid capacitors. Energy Storage Mater. 2020;25:636.
[14]
Liu B, Lei D, Wang J, Zhang Q, Zhang Y, He W, Zheng H, Sa B, Xie Q, Peng DL. 3D uniform nitrogen-doped carbon skeleton for ultra-stable sodium metal anode. Nano Res. 2020;13:2136.
[15]
Guo YG, Hu JS, Wan LJ. Nanostructured materials for electrochemical energy conversion and storage devices. Adv Mater. 2008;20(15):2878.
[16]
Jiang Y, Yao Y, Shi J, Zeng L, Gu L, Yu Y. One-dimensional Na3V2(PO4)3/C nanowires as cathode materials for long-life and high rate Na-ion batteries. ChemNanoMat. 2016;2(7):726.
[17]
Gao S, Wang N, Li S, Li D, Cui Z, Yue G, Liu J, Zhao X, Jiang L, Zhao Y. A multi-wall Sn/SnO2@carbon hollow nanofiber anode material for high-rate and long-life lithium-ion batteries. Angew Chem Int Ed Engl. 2020;59(6):2465.
[18]
Wu Y, Wen Z, Li J. Hierarchical carbon-coated LiFePO4 nanoplate microspheres with high electrochemical performance for Li-ion batteries. Adv Mater. 2011;23(9):1126.
[19]
Qi J, Lai X, Wang J, Tang H, Ren H, Yang Y, Jin Q, Zhang L, Yu R, Ma G, Su Z, Zhao H, Wang D. Multi-shelled hollow micro-/nanostructures. Chem Soc Rev. 2015;44(19):6749.
[20]
Yang Y, Wei WF. Electrochemical mechanism of high Na-content P2-type layered oxides for sodium-ion batteries. Rare Met. 2020;39(4):332.
[21]
Yu P, Tang W, Wu FF, Zhang C, Luo HY, Liu H, Wang ZG. Recent progress in plant-derived hard carbon anode materials for sodium-ion batteries: a review. Rare Met. 2020;39(9):1019.
[22]
Yang J, Li D, Wang X, Zhang X, Xu J, Chen J. Constructing micro-nano Na3V2(PO4)3/C architecture for practical high-loading electrode fabrication as superior-rate and ultralong-life sodium ion battery cathode. Energy Storage Mater. 2020;24:694.
[23]
Xu Y, Wei Q, Xu C, Li Q, An Q, Zhang P, Sheng J, Zhou L, Mai L. Layer-by-layer Na3V2(PO4)3 embedded in reduced graphene oxide as superior rate and ultralong-life sodium-ion battery cathode. Adv Energy Mater. 2016;6:1600389.
[24]
Gu E, Xu J, Du Y, Ge X, Zhu X, Bao J, Zhou X. Understanding the influence of different carbon matrix on the electrochemical performance of Na3V2(PO4)3 cathode for sodium-ion batteries. J Alloys Compd. 2019;788:240.
[25]
Chang X, Zhu Q, Sun N, Guan Y, Wang R, Zhao J, Feng M, Xu B. Graphene-bound Na3V2(PO4)3 film electrode with excellent cycle and rate performance for Na-ion batteries. Electrochim Acta. 2018;269:282.
[26]
Zhang X, Rui X, Chen D, Tan H, Yang D, Huang S, Yu Y. Na3V2(PO4)3: an advanced cathode for sodium-ion batteries. Nanoscale. 2019;11(6):2556.
[27]
Fang Y, Xiao L, Ai X, Cao Y, Yang H. Hierarchical carbon framework wrapped Na3V2(PO4)3 as a superior high-rate and extended lifespan cathode for sodium-ion batteries. Adv Mater. 2015;27(39):5895.
[28]
Chen H, Huang Y, Mao G, Tong H, Yu W, Zheng J, Ding Z. Reduced graphene oxide decorated Na3V2(PO4)3 microspheres as cathode material with advanced sodium storage performance. Front Chem. 2018;6:174.
[29]
Song J, Guo X, Zhang J, Chen Y, Zhang C, Luo L, Wang F, Wang G. Rational design of free-standing 3D porous MXene/rGO hybrid aerogels as polysulfide reservoirs for high-energy lithium-sulfur batteries. J Mater Chem A. 2019;7(11):6507.
[30]
Li J, Zhang H, Luo L, Li H, He J, Zu H, Liu L, Liu H, Wang F, Song J. Blocking polysulfides with a Janus Fe3C/N-CNF@RGO electrode via physiochemical confinement and catalytic conversion for high-performance lithium–sulfur batteries. J Mater Chem A. 2021;9(4):2205.
[31]
Rui X, Sun W, Wu C, Yu Y, Yan Q. An advanced sodium-ion battery composed of carbon coated Na3V2(PO4)3 in a porous graphene network. Adv Mater. 2015;27(42):6670.
[32]
Li S, Dong Y, Xu L, Xu X, He L, Mai L. Effect of carbon matrix dimensions on the electrochemical properties of Na3V2(PO4)3 nanograins for high-performance symmetric sodium-ion batteries. Adv Mater. 2014;26:3545.
[33]
Toby BH, Von Dreele RB. GSAS-II: the genesis of a modern open-source all purpose crystallography software package. J Appl Cryst. 2013;46(2):544.
[34]
Lim SY, Kim H, Shakoor RA, Jung Y, Choi JW. Electrochemical and thermal properties of NASICON structured Na3V2(PO4)3 as a sodium rechargeable battery cathode: a combined experimental and theoretical study. J Electrochem Soc. 2012;159(9):A1393.
[35]
Jian Z, Han W, Lu X, Yang H, Hu YS, Zhou J, Zhou Z, Li J, Chen W, Chen D. Superior electrochemical performance and storage mechanism of Na3V2(PO4)3 cathode for room-temperature sodium-ion batteries. Adv Energy Mater. 2013;3(2):156.
[36]
Xu G, Sun G. Mg2+-doped Na3V2(PO4)3/C decorated with graphene sheets: an ultrafast Na-storage cathode for advanced energy storage. Ceram Int. 2016;42(13):14774.
[37]
Li S, Ge P, Zhang C, Sun W, Hou H, Ji X. The electrochemical exploration of double carbon-wrapped Na3V2(PO4)3: towards long-time cycling and superior rate sodium-ion battery cathode. J Power Sources. 2017;366:249.
[38]
Yang F, Zhang Z, Du K, Zhao X, Chen W, Lai Y, Li J. Dopamine derived nitrogen-doped carbon sheets as anode materials for high-performance sodium ion batteries. Carbon. 2015;91:88.
[39]
Ren W, Zheng Z, Xu C, Niu C, Wei Q, An Q, Zhao K, Yan M, Qin M, Mai L. Self-sacrificed synthesis of three-dimensional Na3V2(PO4)3 nanofiber network for high-rate sodium-ion full batteries. Nano Energy. 2016;25:145.
[40]
Wang H, Jiang D, Zhang Y, Li G, Lan X, Zhong H, Zhang Z, Jiang Y. Self-combustion synthesis of Na3V2(PO4)3 nanoparticles coated with carbon shell as cathode materials for sodium-ion batteries. Electrochim Acta. 2015;155:23.
[41]
Aragón MJ, Lavela P, Ortiz GF, Alcántara R, Tirado JL. On the effect of silicon substitution in Na3V2(PO4)3 on the electrochemical behavior as cathode for sodium-ion batteries. ChemElectroChem. 2018;5(2):367.
[42]
Huang HB, Luo SH, Liu CL, Yang Y, Zhai YC, Chang LJ, Li MQ. Double-carbon coated Na3V2(PO4)3 as a superior cathode material for Na-ion batteries. Appl Surf Sci. 2019;487:1159.
[43]
Liu J, Tang K, Song K, van Aken PA, Yu Y, Maier J. Electrospun Na3V2(PO4)3/C nanofibers as stable cathode materials for sodium-ion batteries. Nanoscale. 2014;6(10):5081.
[44]
Li X, Huang Y, Wang J, Miao L, Li Y, Liu Y, Qiu Y, Fang C, Han J, Huang Y. High valence Mo-doped Na3V2(PO4)3/C as a high rate and stable cycle-life cathode for sodium battery. J Mater Chem A. 2018;6(4):1390.
[45]
Ko JS, Doan-Nguyen Vicky VT, Kim HS, Petrissans X, DeBlock RH, Choi CS, Long JW, Dunn BS. High-rate capability of Na2FePO4F nanoparticles by enhancing surface carbon functionality for Na-ion batteries. J Mater Chem A. 2017;5(35):18707.
[46]
Jiang Y, Yang Z, Li W, Zeng L, Pan F, Wang M, Wei X, Hu G, Gu L, Yu Y. Nanoconfined carbon-coated Na3V2(PO4)3 particles in mesoporous carbon enabling ultralong cycle life for sodium-ion batteries. Adv Energy Mater. 2015;5(10):1402104.
[47]
Wang E, Chen M, Liu X, Liu Y, Guo H, Wu Z, Xiang W, Zhong B, Guo X, Chou S, Dou SX. Organic cross-linker enabling a 3D porous skeleton-supported Na3V2(PO4)3/carbon composite for high power sodium-ion battery cathode. Small Methods. 2018;3(4):1800169.
[48]
Xiao J, Li X, Tang K, Wang D, Long M, Gao H, Chen W, Liu C, Liu H, Wang G. Recent progress of emerging cathode materials for sodium ion batteries. Mater Chem Front. 2021;5:3735.
[49]
Zhang H, Qin B, Buchholz D, Passerini S. High-efficiency sodium-ion battery based on NASICON electrodes with high power and long lifespan. ACS Appl Energy Mater. 2018;1(11):6425.
[50]
Liang X, Ou X, Zheng F, Pan Q, Liu M. Surface modification of Na3V2(PO4)3 by nitrogen and sulfur dual-doped carbon layer with advanced sodium storage property. ACS Appl Mater Interfaces. 2017;9(15):13151.
[51]
Ma L, Hou B, Shang N, Zhang S, Wang C, Zong L, Song J, Wang J, Zhao X. The precise synthesis of twin-born Fe3O4/FeS/carbon nanosheets for high-rate lithium-ion batteries. Mater Chem Front. 2021;5:4579.
[52]
Yang X, Zu H, Luo L, Zhang H, Li J, Yi X, Liu H, Wang F, Song J. Synergistic tungsten oxide/N, S co-doped carbon nanofibers interlayer as anchor of polysulfides for high-performance lithium-sulfur batteries. J Alloys Compd. 2020;833:154969.
[53]
Liu H, Liu X, Li W, Guo X, Wang Y, Wang G, Zhao D. Porous carbon composites for next generation rechargeable lithium batteries. Adv Energy Mater. 2017;7:1700283.
[54]
Metadaten
Titel
Delicate synthesis of quasi-inverse opal structural Na3V2(PO4)3/N-C and Na4MnV(PO4)3/N-C as cathode for high-rate sodium-ion batteries
verfasst von
Xin-Ran Qi
Yuan Liu
Lin-Lin Ma
Bao-Xiu Hou
Hong-Wei Zhang
Xiao-Hui Li
Ya-Shi Wang
Yi-Qing Hui
Ruo-Xun Wang
Chong-Yang Bai
Hao Liu
Jian-Jun Song
Xiao-Xian Zhao
Publikationsdatum
19.01.2022
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 5/2022
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-021-01900-3

Weitere Artikel der Ausgabe 5/2022

Rare Metals 5/2022 Zur Ausgabe

Original Article

In-situ constructed three-dimensional MoS2–MoN heterostructure as the cathode of lithium–sulfur battery

Letter

Realizing remarkable sodium storage performance of a Sn-based anode material with an oxide-alloy intergrowth structure

OriginalPaper

Enhancement in photovoltaic properties of Nd:SnS films prepared by low-cost NSP method

Review

Recent developments in nonferrous metals and related materials for biomedical applications in China: a review

Mini Review

Mechanisms and applications of layer/spinel phase transition in Li- and Mn-rich cathodes for lithium-ion batteries

Letter

UV-activated single-layer WSe2 for highly sensitive NO2 detection

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise