Skip to main content
Erschienen in: Cellulose 8/2017

24.05.2017 | Original Paper

Pyrolysed cellulose nanofibrils and dandelion pappus in supercapacitor application

verfasst von: Juhani Virtanen, Arno Pammo, Jari Keskinen, Essi Sarlin, Sampo Tuukkanen

Erschienen in: Cellulose | Ausgabe 8/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Dandelion pappus and wood based nanocellulose fibrils were combined to form films that were subsequently pyrolyzed under low-pressure conditions in a carbon monoxide (CO) rich atmosphere to make supercapacitor electrode material. The electrodes were prepared from these materials and pyrolysed under low-pressure conditions in a carbon monoxide-rich atmosphere. The electrode materials and assembled supercapacitors were electrically and structurally characterized. The assembled six supercapacitors showed specific capacitances per electrode ranging from 1 to 6 F/g and surface resistance of pyrolyzed electrodes ranging from 30 to 170 Ω/□. Finally, equivalent series resistance and leakage current measurements were conducted for three samples, resulting values from 125 to 500 Ω and from 0.5 to 5.5 µA, respectively.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Hale AN, Imfeld SM, Hart CE, Gribbins KM, Yoder JA, Collier MH (2010) Reduced seed germination after pappus removal in the North American dandelion (Taraxacum officinale; Asteraceae). Weed Sci 58(4):420–425. doi:10.1614/WS-D-10-00036.1 CrossRef Hale AN, Imfeld SM, Hart CE, Gribbins KM, Yoder JA, Collier MH (2010) Reduced seed germination after pappus removal in the North American dandelion (Taraxacum officinale; Asteraceae). Weed Sci 58(4):420–425. doi:10.​1614/​WS-D-10-00036.​1 CrossRef
Zurück zum Zitat Isoniemi T, Tuukkanen S, Cameron DC, Simonen J, Toppari JJ (2015) Measuring optical anisotropy in poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) films with added graphene. Org Electron 25:317–323. doi:10.1016/j.orgel.2015.06.037 CrossRef Isoniemi T, Tuukkanen S, Cameron DC, Simonen J, Toppari JJ (2015) Measuring optical anisotropy in poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) films with added graphene. Org Electron 25:317–323. doi:10.​1016/​j.​orgel.​2015.​06.​037 CrossRef
Zurück zum Zitat Keskinen J, Lehtimäki S, Dastpak A, Tuukkanen S, Flyktman T, Kraft T, Railanmaa A, Lupo D (2016) Architectural modifications for flexible supercapacitor performance optimization. Electron Mater Lett 12:795–803. doi:10.1007/s13391-016-6141-y CrossRef Keskinen J, Lehtimäki S, Dastpak A, Tuukkanen S, Flyktman T, Kraft T, Railanmaa A, Lupo D (2016) Architectural modifications for flexible supercapacitor performance optimization. Electron Mater Lett 12:795–803. doi:10.​1007/​s13391-016-6141-y CrossRef
Zurück zum Zitat Lehtimäki S, Suominen M, Damlin P, Tuukkanen S, Kvarnström C, Lupo D (2015) Preparation of supercapacitors on flexible substrates with electrodeposited PEDOT/graphene composites. ACS Appl Mater Interface 7(40):22137–22147. doi:10.1021/acsami.5b05937 CrossRef Lehtimäki S, Suominen M, Damlin P, Tuukkanen S, Kvarnström C, Lupo D (2015) Preparation of supercapacitors on flexible substrates with electrodeposited PEDOT/graphene composites. ACS Appl Mater Interface 7(40):22137–22147. doi:10.​1021/​acsami.​5b05937 CrossRef
Zurück zum Zitat Lehtimäki S, Tuukkanen S, Pörhönen J, Moilanen P, Virtanen J, Honkanen M, Lupo D (2014) Low-cost, solution processable carbon nanotube supercapacitors and their characterization. Appl Phys A 117(3):1329–1334. doi:10.1007/s00339-014-8547-4 CrossRef Lehtimäki S, Tuukkanen S, Pörhönen J, Moilanen P, Virtanen J, Honkanen M, Lupo D (2014) Low-cost, solution processable carbon nanotube supercapacitors and their characterization. Appl Phys A 117(3):1329–1334. doi:10.​1007/​s00339-014-8547-4 CrossRef
Zurück zum Zitat Meng Q, Wang Q, Liu H, Jiang L (2014) A bio-inspired flexible fiber array with an open radial geometry for highly efficient liquid transfer. NPG Asia Mater 6(9):e125. doi:10.1038/am.2014.70 CrossRef Meng Q, Wang Q, Liu H, Jiang L (2014) A bio-inspired flexible fiber array with an open radial geometry for highly efficient liquid transfer. NPG Asia Mater 6(9):e125. doi:10.​1038/​am.​2014.​70 CrossRef
Zurück zum Zitat Moon RJ, Martini A, Nairn J, Simonsen J, Youngblood J (2011) Cellulose nanomaterials review: structure properties and nanocomposites. Chem Soc Rev 40(7):3941–3994. doi:10.1039/C0CS00108B CrossRef Moon RJ, Martini A, Nairn J, Simonsen J, Youngblood J (2011) Cellulose nanomaterials review: structure properties and nanocomposites. Chem Soc Rev 40(7):3941–3994. doi:10.​1039/​C0CS00108B CrossRef
Zurück zum Zitat Österberg M, Vartiainen J, Lucenius J, Hippi U, Seppälä J, Serimaa R, Laine J (2013) A fast method to produce strong NFC films as a platform for barrier and functional materials. ACS Appl Mater Interface 5(11):4640–4647. doi:10.1021/am401046x CrossRef Österberg M, Vartiainen J, Lucenius J, Hippi U, Seppälä J, Serimaa R, Laine J (2013) A fast method to produce strong NFC films as a platform for barrier and functional materials. ACS Appl Mater Interface 5(11):4640–4647. doi:10.​1021/​am401046x CrossRef
Zurück zum Zitat Pettersson F, Keskinen J, Remonen T, von Hertzen L, Jansson E, Tappura K, Zhang Y, Wilén C-E, Österbacka R (2014) Printed environmentally friendly supercapacitors with ionic liquid electrolytes on paper. J Power Sources 271:298–304. doi:10.1016/j.jpowsour.2014.08.020 CrossRef Pettersson F, Keskinen J, Remonen T, von Hertzen L, Jansson E, Tappura K, Zhang Y, Wilén C-E, Österbacka R (2014) Printed environmentally friendly supercapacitors with ionic liquid electrolytes on paper. J Power Sources 271:298–304. doi:10.​1016/​j.​jpowsour.​2014.​08.​020 CrossRef
Zurück zum Zitat Rajala S, Siponkoski T, Sarlin E, Mettänen M, Vuoriluoto M, Pammo A, Juuti J, Rojas OJ, Franssila S, Tuukkanen S (2016) Cellulose nanofibril film as a piezoelectric sensor material. ACS Appl Mater Interface 8(24):15607–15614. doi:10.1021/acsami.6b03597 CrossRef Rajala S, Siponkoski T, Sarlin E, Mettänen M, Vuoriluoto M, Pammo A, Juuti J, Rojas OJ, Franssila S, Tuukkanen S (2016) Cellulose nanofibril film as a piezoelectric sensor material. ACS Appl Mater Interface 8(24):15607–15614. doi:10.​1021/​acsami.​6b03597 CrossRef
Zurück zum Zitat Schmidt T, Lenders M, Hillebrand A, van Deenen N, Munt O, Reichelt R, Eisenreich W, Fischer R, Prüfer D, Gronover C (2010) Characterization of rubber particles and rubber chain elongation in Taraxacum koksaghyz. BMC Biochem. doi:10.1186/1471-2091-11-11 Schmidt T, Lenders M, Hillebrand A, van Deenen N, Munt O, Reichelt R, Eisenreich W, Fischer R, Prüfer D, Gronover C (2010) Characterization of rubber particles and rubber chain elongation in Taraxacum koksaghyz. BMC Biochem. doi:10.​1186/​1471-2091-11-11
Zurück zum Zitat Torvinen K, Lehtimäki S, Keränen JT, Sievänen J, Vartiainen J, Hellén E, Lupo D, Tuukkanen S (2015) Pigment-cellulose nanofibril composite and its application as a separator-substrate in printed supercapacitors. Electron Mater Lett 11(6):1040–1047. doi:10.1007/s13391-015-5195-6 CrossRef Torvinen K, Lehtimäki S, Keränen JT, Sievänen J, Vartiainen J, Hellén E, Lupo D, Tuukkanen S (2015) Pigment-cellulose nanofibril composite and its application as a separator-substrate in printed supercapacitors. Electron Mater Lett 11(6):1040–1047. doi:10.​1007/​s13391-015-5195-6 CrossRef
Zurück zum Zitat Tuukkanen S, Lehtimaki S, Jahangir F, Eskelinen A-P, Lupo D, Franssila S (2014). Printable and disposable supercapacitor from nanocellulose and carbon nanotubes. In Proceedings of the 5th electronics system-integration technology conference (ESTC). IEEE, pp 1–6. DOI: 10.1109/ESTC.2014.6962740 Tuukkanen S, Lehtimaki S, Jahangir F, Eskelinen A-P, Lupo D, Franssila S (2014). Printable and disposable supercapacitor from nanocellulose and carbon nanotubes. In Proceedings of the 5th electronics system-integration technology conference (ESTC). IEEE, pp 1–6. DOI: 10.​1109/​ESTC.​2014.​6962740
Zurück zum Zitat Vuorinen T, Zakrzewski M, Rajala S, Lupo D, Vanhala J, Palovuori K, Tuukkanen S (2014) Printable, transparent, and flexible touch panels working in sunlight and moist environments. Adv Funct Mater 24(40):6340–6347. doi:10.1002/adfm.201401140 CrossRef Vuorinen T, Zakrzewski M, Rajala S, Lupo D, Vanhala J, Palovuori K, Tuukkanen S (2014) Printable, transparent, and flexible touch panels working in sunlight and moist environments. Adv Funct Mater 24(40):6340–6347. doi:10.​1002/​adfm.​201401140 CrossRef
Zurück zum Zitat Wang Z, Carlsson DO, Tammela P, Hua K, Zhang P, Nyholm L, Strømme M (2015) Surface modified nanocellulose fibers yield conducting polymer-based flexible supercapacitors with enhanced capacitances. ACS Nano 9(7):7563–7571. doi:10.1021/acsnano.5b02846 CrossRef Wang Z, Carlsson DO, Tammela P, Hua K, Zhang P, Nyholm L, Strømme M (2015) Surface modified nanocellulose fibers yield conducting polymer-based flexible supercapacitors with enhanced capacitances. ACS Nano 9(7):7563–7571. doi:10.​1021/​acsnano.​5b02846 CrossRef
Zurück zum Zitat Wang Z, Tammela P, Huo J, Zhang P, Strømme M, Nyholm L (2016) Solution-processed poly(3,4-ethylenedioxythiophene) nanocomposite paper electrodes for high-capacitance flexible supercapacitors. J Mater Chem A 4:1714–1722. doi:10.1039/C5TA10122K CrossRef Wang Z, Tammela P, Huo J, Zhang P, Strømme M, Nyholm L (2016) Solution-processed poly(3,4-ethylenedioxythiophene) nanocomposite paper electrodes for high-capacitance flexible supercapacitors. J Mater Chem A 4:1714–1722. doi:10.​1039/​C5TA10122K CrossRef
Zurück zum Zitat Ward H. Herbal Manual. The C. W. Daniel Company Ltd, London. 1936. ISBN-10: 0852430086 Ward H. Herbal Manual. The C. W. Daniel Company Ltd, London. 1936. ISBN-10: 0852430086
Zurück zum Zitat Wu XL, Wen T, Guo HL, Yang S, Wang X, Xu AW (2013b) Biomass-derived sponge-like carbonaceous hydrogels and aerogels for supercapacitors. ACS Nano 7(4):3589–3597. doi:10.1021/nn400566d CrossRef Wu XL, Wen T, Guo HL, Yang S, Wang X, Xu AW (2013b) Biomass-derived sponge-like carbonaceous hydrogels and aerogels for supercapacitors. ACS Nano 7(4):3589–3597. doi:10.​1021/​nn400566d CrossRef
Zurück zum Zitat Zolin L, Nair JR, Beneventi D, Bella F, Destro M, Jagdale P, Cannavaroe I, Tagliaferroe A, Chaussy D, Geobaldoe F, Gerbaldi C (2016) A simple route toward next-gen green energy storage concept by nanofibres-based self-supporting electrodes and a solid polymeric design. Carbon 107:811–822. doi:10.1016/j.carbon.2016.06.076 CrossRef Zolin L, Nair JR, Beneventi D, Bella F, Destro M, Jagdale P, Cannavaroe I, Tagliaferroe A, Chaussy D, Geobaldoe F, Gerbaldi C (2016) A simple route toward next-gen green energy storage concept by nanofibres-based self-supporting electrodes and a solid polymeric design. Carbon 107:811–822. doi:10.​1016/​j.​carbon.​2016.​06.​076 CrossRef
Metadaten
Titel
Pyrolysed cellulose nanofibrils and dandelion pappus in supercapacitor application
verfasst von
Juhani Virtanen
Arno Pammo
Jari Keskinen
Essi Sarlin
Sampo Tuukkanen
Publikationsdatum
24.05.2017
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 8/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-017-1332-8

Weitere Artikel der Ausgabe 8/2017

Cellulose 8/2017 Zur Ausgabe