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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 7/2016

17.03.2016

Photoelectrochemical properties of lead-free ferroelectric ceramic Ba(Ti0.96Mg0.013Nb0.026)O3: application to solar conversion of eosin

verfasst von: N. Bensemma, G. Rekhila, N. Boutal, K. Taïbi, M. Trari

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 7/2016

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Abstract

The lead-free Ba(Ti0.96Mg0.013Nb0.026)O3 composition has been prepared by solid state reaction. The room temperature X-ray diffraction revealed a perovskite phase with a tetragonal symmetry. The complex dielectric permittivity measured on cooling from 470 to 150 K in the frequency range (102–106 Hz) indicated a ferroelectric behavior and exhibited a large electromechanical response. This ferroelectric perovskite showed photoelectrochemical properties with an optical gap of 2.90 eV, n-type conduction and a flat band potential of −0.57 V SCE . As application, the oxide is successfully tested for the eosin oxidation under solar light. At pH ~ 6.3, 90 % of eosin (15 mg L−1) disappeared after 6 h of illumination for a catalyst dose of 2.5 g L−1.
Vorheriger Artikel Preparation of hierarchical CdS structures and effect of sodium dodecyl benzene sulfonate (SDBS) on the morphologies
Nächster Artikel A high sensitive and low detection limit of formaldehyde gas sensor based on hierarchical flower-like CuO nanostructure fabricated by sol–gel method

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Metadaten
Titel
Photoelectrochemical properties of lead-free ferroelectric ceramic Ba(Ti0.96Mg0.013Nb0.026)O3: application to solar conversion of eosin
verfasst von
N. Bensemma
G. Rekhila
N. Boutal
K. Taïbi
M. Trari
Publikationsdatum
17.03.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 7/2016
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-016-4625-z

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