nach oben

Cellulose

Erschienen in:

27.03.2022 | Original Research

The H-bond evolution of cellulose nanofibrils treated with choline chloride/oxalic acid

verfasst von: Zhenke Wei, Daiqi Wang, Yehong Chen, Dongmei Yu, Qijun Ding, Ronggang Li, Chaojun Wu

Erschienen in: Cellulose | Ausgabe 7/2022

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The fracture and recombination of its H-bond network have significant influence on the pore structure of nanocellulose and its materials. Deep eutectic solvents (DESs) have been widely used in the cellulose dissolution and nanocellulose treatment because of their efficient H-bond cleavage in cellulose; however, the H-bond evolution mechanism is still not fully understood. The main objective of the present work was to treat cellulose nanofibrils (CNFs) using a DES system based on choline chloride and oxalic acid. The effect of DES treatment on the H-bond, micro-structure, and properties of CNFs were analyzed. The results confirmed that choline chloride/oxalic acid effectively destroyed the intermolecular and intramolecular H-bonds in CNFs, thereby reducing the H-bond energy. This resulted in a decrease in the intramolecular H-bond contents, and an increase in the intermolecular H-bond contents of the CNFs. The changes in the three types of H-bond were independent, and their fracture sequence was of the order v(O(3)H…O(5) intramolecular H-bond) > v(O(6)H…O(3′) intermolecular H-bond) > v(O(2)H…O(6) intramolecular H-bond). Moreover, H-bond destruction improved the crystallinity index and crystallite size of the CNFs. The changes in the crystal parameters further led to an increase in the thermal stability. This work provides a theoretical basis for the treatment of CNFs by DESs, which is critical for the H-bond evolution principle of CNFs.

Graphic Abstract

Vorheriger Artikel Phase transitions of cellulose nanocrystal suspensions from nonlinear oscillatory shear

Nächster Artikel Process optimization and comprehensive utilization of recyclable deep eutectic solvent for the production of ramie cellulose fibers

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Apostolopoulou-Kalkavoura V, Munier P, Bergstrom L (2021) Thermally insulating nanocellulose-based materials. Adv Mater 33:2001839–2001855. https://doi.org/10.1002/adma.202001839CrossRef

Cañas-Gutiérrez A, Martinez-Correa E, Suárez-Avendaño D, Arboleda-Toro D, Castro-Herazo C (2020) Influence of bacterial nanocellulose surface modification on calcium phosphates precipitation for bone tissue engineering. Cellulose 27:10747–10763. https://doi.org/10.1007/s10570-020-03470-6CrossRef

Dhawan U, Pan HA, Shie MJ, Chu YH, Huang GS, Chen PC, Chen WL (2017) The spatiotemporal control of osteoblast cell growth, behavior, and function dictated by nanostructured stainless steel artificial microenvironments. Nanoscale Res Lett 12:86–95. https://doi.org/10.1186/s11671-016-1810-1CrossRefPubMedPubMedCentral

Ding Q et al (2021) Understanding the evolution of cellulose fibers during enzyme treatment. Ind Crop Prod 171:113983–113989. https://doi.org/10.1016/j.indcrop.2021.113983CrossRef

Dorishetty P et al (2020) Tunable biomimetic hydrogels from silk fibroin and nanocellulose. ACS Sustain Chem Eng 8:2375–2389. https://doi.org/10.1021/acssuschemeng.9b05317CrossRef

Du P, Ding Q, Zhao C, Jiang Y, Han W, Li X (2021) The fluorine-free coating has excellent hydrophobic and oleophobic properties for porous cellulose-based materials. Cellulose 28:6133–6146. https://doi.org/10.1007/s10570-021-03959-8CrossRef

Dufresne A (2017) Cellulose nanomaterial reinforced polymer nanocomposites. Curr Opin Colloid Interface Sci 29:1–8. https://doi.org/10.1016/j.cocis.2017.01.004CrossRef

Ferreira FV, Otoni CG, De France KJ, Barud HS, Lona LMF, Cranston ED, Rojas OJ (2020) Porous nanocellulose gels and foams: Breakthrough status in the development of scaffolds for tissue engineering. Mater Today 37:126–141. https://doi.org/10.1016/j.mattod.2020.03.003CrossRef

Ge S, Chen X, Li D, Liu Z, Ouyang H, Peng W, Zhang Z (2018) Hemicellulose structural changes during steam pretreatment and biogradation of Lentinus edodes. Arab J Chem 11:771–781. https://doi.org/10.1016/j.arabjc.2017.12.022CrossRef

Ghafari R, Jonoobi M, Amirabad LM, Oksman K, Taheri AR (2019) Fabrication and characterization of novel bilayer scaffold from nanocellulose based aerogel for skin tissue engineering applications. Int J Biol Macromol 136:796–803. https://doi.org/10.1016/j.ijbiomac.2019.06.104CrossRefPubMed

Guo Y, Wu P (2008) Investigation of the hydrogen-bond structure of cellulose diacetate by two-dimensional infrared correlation spectroscopy. Carbohyd Polym 74:509–513. https://doi.org/10.1016/j.carbpol.2008.04.005CrossRef

Holzwarth U, Gibson N (2011) The Scherrer equation versus the ‘Debye–Scherrer equation’. Nat Nanotechnol 6:534. https://doi.org/10.1038/nnano.2011.145CrossRefPubMed

Hong S, Yuan Y, Li P, Zhang K, Lian H, Liimatainen H (2020) Enhancement of the nanofibrillation of birch cellulose pretreated with natural deep eutectic solvent. Iud Crop Prod 154:112677–112684. https://doi.org/10.1016/j.indcrop.2020.112677CrossRef

Huang D, Wu M, Wang C, Kuga S, Huang Y (2020) Effect of partial dehydration on freeze-drying of aqueous nanocellulose suspension. ACS Sustain Chem Eng 8:11389–11395. https://doi.org/10.1021/acssuschemeng.0c03688CrossRef

Ji B, Cai Z, Sun G, Yan K (2020) Hydroxyl changing mechanism of cotton cellulose during alkaline treatment characterized by ATR-FTIR in combination with two-dimensional correlation spectroscopy. AATCC J Res 7:1–8. https://doi.org/10.14504/ajr.7.5.1CrossRef

Kim U-J, Eom SH, Wada M (2010) Thermal decomposition of native cellulose: influence on crystallite size. Polym Degrad Stabil 95:778–781. https://doi.org/10.1016/j.polymdegradstab.2010.02.009CrossRef

Kim S, Han DY, Chen Z, Lee WG (2018) Dependence of cell adhesion on extracellular matrix materials formed on pore bridge boundaries by nanopore opening and closing. Geom Anal 143:2141–2149. https://doi.org/10.1039/c8an00429cCrossRef

Lim J et al (2018) Constrained adherable area of nanotopographic surfaces promotes cell migration through the regulation of focal adhesion via focal adhesion kinase/Rac1 activation. ACS Appl Mater Interfaces 10:14331–14341. https://doi.org/10.1021/acsami.7b18954CrossRefPubMed

Lim W-L, Gunny AAN, Kasim FH, AlNashef IM, Arbain D (2019) Alkaline deep eutectic solvent: a novel green solvent for lignocellulose pulping. Cellulose 26:4085–4098. https://doi.org/10.1007/s10570-019-02346-8CrossRef

Lim W-L, Gunny AAN, Kasim FH, Gopinath SCB, Kamaludin NHI, Arbain D (2021) Cellulose nanocrystals from bleached rice straw pulp: acidic deep eutectic solvent versus sulphuric acid hydrolyses. Cellulose 28:6183–6199. https://doi.org/10.1007/s10570-021-03914-7CrossRef

Ling Z et al (2018) Structural variations of cotton cellulose nanocrystals from deep eutectic solvent treatment: micro and nano scale. Cellulose 26:861–876. https://doi.org/10.1007/s10570-018-2092-9CrossRef

Liu Y et al (2017) Efficient cleavage of strong hydrogen bonds in cotton by deep eutectic solvents and facile fabrication of cellulose nanocrystals in high yields. ACS Sustain Chem Eng 5:7623–7631. https://doi.org/10.1021/acssuschemeng.7b00954CrossRef

Miettunen K, Vapaavuori J, Tiihonen A, Poskela A, Lahtinen P, Halme J, Lund P (2014) Nanocellulose aerogel membranes for optimal electrolyte filling in dye solar cells. Nano Energy 8:95–102. https://doi.org/10.1016/j.nanoen.2014.05.013CrossRef

Noda I (1990) Two-dimensional infrared (2D IR) spectroscopy: theory and applications. Appl Spectrosc 44:550–561. https://doi.org/10.1366/0003702904087398CrossRef

Peng Y, Wu S (2010) The structural and thermal characteristics of wheat straw hemicellulose. J Anal Appl Pyrol 88:134–139. doi:https://doi.org/10.1016/j.jaap.2010.03.006CrossRef

Salviati S, Carosio F, Cantamessa F, Medina L, Berglund LA, Saracco G, Fina A (2020) Ice-templated nanocellulose porous structure enhances thermochemical storage kinetics in hydrated salt/graphite composites. Renew Energy 160:698–706. https://doi.org/10.1016/j.renene.2020.07.036CrossRef

Sawada D et al (2013) Structure and dynamics of a complex of cellulose with EDA: insights into the action of amines on cellulose. Cellulose 20:1563–1571. https://doi.org/10.1007/s10570-013-9974-7CrossRef

Segal L, Creely JJ, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786–794. https://doi.org/10.1177/004051755902901003CrossRef

Shen T, Gnanakaran S (2009) The stability of cellulose: a statistical perspective from a coarse-grained model of hydrogen-bond networks. Biophys J 96:3032–3040. https://doi.org/10.1016/j.bpj.2008.12.3953CrossRefPubMedPubMedCentral

Smirnov MA et al (2020) Green method for preparation of cellulose nanocrystals using deep eutectic solvent. Cellulose 27:4305–4317. https://doi.org/10.1007/s10570-020-03100-1CrossRef

Sultan S, Mathew AP (2018) 3D printed scaffolds with gradient porosity based on a cellulose nanocrystal hydrogel. Nanoscale 10:4421–4431. https://doi.org/10.1039/c7nr08966jCrossRefPubMed

Sun Y, Chu Y, Wu W, Xiao H (2021) Nanocellulose-based lightweight porous materials. Rev Carbohydr Polym 255:117489–117507. doi:https://doi.org/10.1016/j.carbpol.2020.117489CrossRef

Thomas B et al (2018) Nanocellulose, a versatile green platform: from biosources to materials and their applications. Chem Rev 118:11575–11625. https://doi.org/10.1021/acs.chemrev.7b00627CrossRefPubMed

Vennestrom PN, Osmundsen CM, Christensen CH, Taarning E (2011) Beyond petrochemicals: the renewable chemicals industry. Angew Chem Int Ed Engl 50:10502–10509. doi:https://doi.org/10.1002/anie.201102117CrossRefPubMed

Wan J, Lian J, Wang Y, Ma Y (2015) Investigation of cellulose supramolecular structure changes during conversion of waste paper in near-critical water on producing 5-hydroxymethyl furfural. Renew Energy 80:132–139. https://doi.org/10.1016/j.renene.2015.01.071CrossRef

Wang S, Gao W, Chen K, Xiang Z, Zeng J, Wang B, Xu J (2018) Deconstruction of cellulosic fibers to fibrils based on enzymatic pretreatment. Bioresour Technol 267:426–430. https://doi.org/10.1016/j.biortech.2018.07.067CrossRefPubMed

Wang H, Li J, Zeng X, Tang X, Sun Y, Lei T, Lin L (2019) Extraction of cellulose nanocrystals using a recyclable deep eutectic solvent. Cellulose 27:1301–1314. https://doi.org/10.1007/s10570-019-02867-2CrossRef

Watanabe A, Morita S, Kokot S, Matsubara M, Fukai K, Ozaki Y (2006) Drying process of microcrystalline cellulose studied by attenuated total reflection IR spectroscopy with two-dimensional correlation spectroscopy and principal component analysis. J Mol Struct 799:102–110. https://doi.org/10.1016/j.molstruc.2006.03.018CrossRef

Xu X, Zhou J, Feng C, Jiang Y, Zhang Q, Shi H (2019) 3D printing algorithm of anisotropic biological scaffold with oxidized nanocellulose and gelatin. J Biomater Sci Polym Ed 30:1260–1275. https://doi.org/10.1080/09205063.2019.1627651CrossRefPubMed

Yang X et al (2019) Facile extraction of thermally stable and dispersible cellulose nanocrystals with high yield via a green and recyclable FeCl3-catalyzed deep eutectic solvent system. ACS Sustain Chem Eng 7:7200–7208. https://doi.org/10.1021/acssuschemeng.9b00209CrossRef

Yin K, Divakar P, Wegst UGK (2019) Plant-derived nanocellulose as structural and mechanical reinforcement of freeze-cast chitosan scaffolds for biomedical applications. Biomacromolecules 20:3733–3745. https://doi.org/10.1021/acs.biomac.9b00784CrossRefPubMedPubMedCentral

Yu Y et al (2019) Systematic hydrogen‐bond manipulations to establish polysaccharide structure–property correlations. Angew Chem Int Ed Engl 58:13127–13132. https://doi.org/10.1002/anie.201906577CrossRefPubMedPubMedCentral

Yu W, Wang C, Yi Y, Wang H, Yang Y, Zeng L, Tan Z (2020) Direct pretreatment of raw ramie fibers using an acidic deep eutectic solvent to produce cellulose nanofibrils in high purity. Cellulose 28:175–188. https://doi.org/10.1007/s10570-020-03538-3CrossRef

Zhang H, Lang J, Lan P, Yang H, Lu J, Wang Z (2020) Study on the dissolution mechanism of cellulose by ChCl-based deep eutectic solvents. Materials 13:278–289. https://doi.org/10.3390/ma13020278CrossRefPubMedCentral

Zhu H et al (2016) Wood-derived materials for green electronics, biological devices, and energy applications. Chem Rev 116:9305–9374. https://doi.org/10.1021/acs.chemrev.6b00225CrossRefPubMed

Zhu Y, Wu C, Yu D, Ding Q, Li R (2021) Tunable micro-structure of dissolving pulp-based cellulose nanofibrils with facile prehydrolysis process. Cellulose 28:3759–3773. https://doi.org/10.1007/s10570-021-03760-7CrossRef

Titel: The H-bond evolution of cellulose nanofibrils treated with choline chloride/oxalic acid
verfasst von: Zhenke Wei
Daiqi Wang
Yehong Chen
Dongmei Yu
Qijun Ding
Ronggang Li
Chaojun Wu
Publikationsdatum: 27.03.2022
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 7/2022
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-022-04517-6

Springer Professional

Abstract

Graphic Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 7/2022

Effect of particle concentration on lubrication performance of cellulose nanocrystalline (CNC) water-based lubricants: mixed lubrication regime

Effect of enzymes on the scouring and bleaching properties of flax roves in supercritical CO2

Highly sensitive and selective fluorescent sensor for Ag+ detection using β-cyclodextrin/chitosan polymer-coated S QDs based on an aggregation-induced quenching mechanism

Exploiting chitosan to improve the interface of nanocellulose reinforced polymer composites

Enhanced mechanical strength and antibacterial properties of Chitosan/Graphene oxide composite fibres

Derived from corn straw cellulose: modified used tire rubber powder composites