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Erschienen in: Cellulose 12/2018

10.10.2018 | Original Paper

A waterborne bio-based polymer pigment: colored regenerated cellulose suspension from waste cotton fabrics

verfasst von: Lei Ding, Yang Jiang, Bijia Wang, Yingzhan Li, Zhiping Mao, Hong Xu, Yi Zhong, Linping Zhang, Xiaofeng Sui

Erschienen in: Cellulose | Ausgabe 12/2018

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Abstract

Waterborne bio-based polymer pigments are promising environmentally friendly coloring materials. In this work, novel colored cellulose suspensions applicable for coloring, labelling and anti-counterfeiting were prepared from waste cotton fabrics. It was demonstrated that cellulose regenerated from a phosphoric acid solution of waste cotton fabrics could be conveniently colored by reacting with reactive dyes. The high specific surface area of the regenerated cellulose (RC) allowed for high color build-up of up to 210 mg/g dye fixation and K/S value of up to 31. The resulting colored regenerated cellulose (CRC) suspension had typical characteristics of regenerated cellulose and was used to color polyurethane (PU). The resulting colored PU films exhibited excellent color fastness/resistance to leaching when soaked in water. This study demonstrated a way of alleviating the environmental burden of waste cotton fabrics by converting them to high value-added colored waterborne cellulose suspension.

Graphical abstract

Preparation and application of CRC suspensions from waste cotton fabrics

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Literatur
Zurück zum Zitat Abitbol T, Palermo A, Moran-Mirabal JM, Cranston ED (2013) Fluorescent labeling and characterization of cellulose nanocrystals with varying charge contents. Biomacromolecules 14:3278–3284CrossRef Abitbol T, Palermo A, Moran-Mirabal JM, Cranston ED (2013) Fluorescent labeling and characterization of cellulose nanocrystals with varying charge contents. Biomacromolecules 14:3278–3284CrossRef
Zurück zum Zitat Ahmed NSE (2005) The use of sodium edate in the dyeing of cotton with reactive dyes. Dyes Pigm 65:221–225CrossRef Ahmed NSE (2005) The use of sodium edate in the dyeing of cotton with reactive dyes. Dyes Pigm 65:221–225CrossRef
Zurück zum Zitat Ashori A, Babaee M, Jonoobi M, Hamzeh Y (2014) Solvent-free acetylation of cellulose nanofibers for improving compatibility and dispersion. Carbohydr Polym 102:369–375CrossRef Ashori A, Babaee M, Jonoobi M, Hamzeh Y (2014) Solvent-free acetylation of cellulose nanofibers for improving compatibility and dispersion. Carbohydr Polym 102:369–375CrossRef
Zurück zum Zitat Beija M, Charreyre M-T, Martinho JMG (2011) Dye-labelled polymer chains at specific sites: synthesis by living/controlled polymerization. Prog Polym Sci 36:568–602CrossRef Beija M, Charreyre M-T, Martinho JMG (2011) Dye-labelled polymer chains at specific sites: synthesis by living/controlled polymerization. Prog Polym Sci 36:568–602CrossRef
Zurück zum Zitat Bekkour K, Sun-Waterhouse D, Wadhwa SS (2014) Rheological properties and cloud point of aqueous carboxymethyl cellulose dispersions as modified by high or low methoxyl pectin. Food Res Int 66:247–256CrossRef Bekkour K, Sun-Waterhouse D, Wadhwa SS (2014) Rheological properties and cloud point of aqueous carboxymethyl cellulose dispersions as modified by high or low methoxyl pectin. Food Res Int 66:247–256CrossRef
Zurück zum Zitat Farahbakhsh N, Venditti RA, Jur JS (2014) Mechanical and thermal investigation of thermoplastic nanocomposite films fabricated using micro- and nano-sized fillers from recycled cotton T-shirts. Cellulose 21:2743–2755CrossRef Farahbakhsh N, Venditti RA, Jur JS (2014) Mechanical and thermal investigation of thermoplastic nanocomposite films fabricated using micro- and nano-sized fillers from recycled cotton T-shirts. Cellulose 21:2743–2755CrossRef
Zurück zum Zitat Farahbakhsh N, Roodposhti PS, Ayoub A, Venditti RA, Jur JS (2015) Melt extrusion of polyethylene nanocomposites reinforced withnanofibrillated cellulose from cotton and wood sources. J Appl Polym Sci 132:41857CrossRef Farahbakhsh N, Roodposhti PS, Ayoub A, Venditti RA, Jur JS (2015) Melt extrusion of polyethylene nanocomposites reinforced withnanofibrillated cellulose from cotton and wood sources. J Appl Polym Sci 132:41857CrossRef
Zurück zum Zitat García A, Gandini A, Labidi J, Belgacem N, Bras J (2016) Industrial and crop wastes: a new source for nanocellulose biorefinery. Ind Crops Prod 93:26–38CrossRef García A, Gandini A, Labidi J, Belgacem N, Bras J (2016) Industrial and crop wastes: a new source for nanocellulose biorefinery. Ind Crops Prod 93:26–38CrossRef
Zurück zum Zitat Han YY, Zhang XX, Wu XD, Lu CH (2015) Flame retardant, heat insulating cellulose aerogels from waste cotton fabrics by in situ formation of magnesium hydroxide nanoparticles in cellulose gel nanostructures. ACS Sustain Chem Eng 3:1853–1859CrossRef Han YY, Zhang XX, Wu XD, Lu CH (2015) Flame retardant, heat insulating cellulose aerogels from waste cotton fabrics by in situ formation of magnesium hydroxide nanoparticles in cellulose gel nanostructures. ACS Sustain Chem Eng 3:1853–1859CrossRef
Zurück zum Zitat Hu Y, Shen BY, Li BT, Xu M, Jiang GQ, Kan CY (2016) Preparation and properties of a novel polymerizable amphiphilic anthraquinone derivative and its cationic colored copolymer latexes. RSC Adv 6:37765–37772CrossRef Hu Y, Shen BY, Li BT, Xu M, Jiang GQ, Kan CY (2016) Preparation and properties of a novel polymerizable amphiphilic anthraquinone derivative and its cationic colored copolymer latexes. RSC Adv 6:37765–37772CrossRef
Zurück zum Zitat Huang J-L, Li C-J, Gray DG (2013) Cellulose nanocrystals incorporating fluorescent methylcoumarin groups. ACS Sustain Chem Eng 1:1160–1164CrossRef Huang J-L, Li C-J, Gray DG (2013) Cellulose nanocrystals incorporating fluorescent methylcoumarin groups. ACS Sustain Chem Eng 1:1160–1164CrossRef
Zurück zum Zitat Jang B, Kim SY, Do JY (2012) Dye-incorporated water-soluble polymer via click triazole formation. Dyes Pigm 94:217–223CrossRef Jang B, Kim SY, Do JY (2012) Dye-incorporated water-soluble polymer via click triazole formation. Dyes Pigm 94:217–223CrossRef
Zurück zum Zitat Jia X, Chen YW, Shi C, Ye YF, Wang P, Zeng XX, Wu T (2013) Preparation and characterization of cellulose regenerated from phosphoric acid. J Agric Food Chem 61:12405–12414CrossRef Jia X, Chen YW, Shi C, Ye YF, Wang P, Zeng XX, Wu T (2013) Preparation and characterization of cellulose regenerated from phosphoric acid. J Agric Food Chem 61:12405–12414CrossRef
Zurück zum Zitat Jiang Y, Liu LL, Wang BJ, Sui XF, Zhong Y, Zhang LP, Mao ZP, Xu H (2018) Cellulose-rich oleogels prepared with an emulsion-templated approach. Food Hydrocolloids 77:460–464CrossRef Jiang Y, Liu LL, Wang BJ, Sui XF, Zhong Y, Zhang LP, Mao ZP, Xu H (2018) Cellulose-rich oleogels prepared with an emulsion-templated approach. Food Hydrocolloids 77:460–464CrossRef
Zurück zum Zitat Jonoobi M, Oladi R, Davoudpour Y, Oksman K, Dufresne A, Hamzeh Y, Davoodi R (2015) Different preparation methods and properties of nanostructured cellulose from various natural resources and residues: a review. Cellulose 22:935–969CrossRef Jonoobi M, Oladi R, Davoudpour Y, Oksman K, Dufresne A, Hamzeh Y, Davoodi R (2015) Different preparation methods and properties of nanostructured cellulose from various natural resources and residues: a review. Cellulose 22:935–969CrossRef
Zurück zum Zitat Leng TY, Jakubek ZJ, Mazloumi M, Leung ACW, Johnston LJ (2017) Ensemble and single particle fluorescence characterization of dye-labeled cellulose nanocrystals. Langmuir 33:8002–8011CrossRef Leng TY, Jakubek ZJ, Mazloumi M, Leung ACW, Johnston LJ (2017) Ensemble and single particle fluorescence characterization of dye-labeled cellulose nanocrystals. Langmuir 33:8002–8011CrossRef
Zurück zum Zitat Li JJ, Song ZQ, Li DG, Shang SB, Guo Y (2014) Cotton cellulose nanofiber-reinforced high density polyethylenecomposites prepared with two different pretreatment methods. Ind Crops Prod 59:318–328CrossRef Li JJ, Song ZQ, Li DG, Shang SB, Guo Y (2014) Cotton cellulose nanofiber-reinforced high density polyethylenecomposites prepared with two different pretreatment methods. Ind Crops Prod 59:318–328CrossRef
Zurück zum Zitat Mao HY, Wang CX, Wang YJ (2015) Synthesis of polymeric dyes based on waterborne polyurethane for improved color stability. New J Chem 39:3543–3550CrossRef Mao HY, Wang CX, Wang YJ (2015) Synthesis of polymeric dyes based on waterborne polyurethane for improved color stability. New J Chem 39:3543–3550CrossRef
Zurück zum Zitat Miranda R, Sosa_Blanco C, Bustos-Martínez D, Vasile C (2007) Pyrolysis of textile wastes. J Anal Appl Pyrolysis 80:489–495CrossRef Miranda R, Sosa_Blanco C, Bustos-Martínez D, Vasile C (2007) Pyrolysis of textile wastes. J Anal Appl Pyrolysis 80:489–495CrossRef
Zurück zum Zitat Moon RJ, Martini A, Nairn J, Simonsen J, Youngblood J (2011) Cellulose nanomaterials review: structure, properties and nanocomposites. Chem Soc Rev 40:3941–3994CrossRef Moon RJ, Martini A, Nairn J, Simonsen J, Youngblood J (2011) Cellulose nanomaterials review: structure, properties and nanocomposites. Chem Soc Rev 40:3941–3994CrossRef
Zurück zum Zitat Nallathambi A, Venkateshwarapuram Rengaswami GD (2016) Salt-free reactive dyeing of cotton hosiery fabrics by exhaust application of cationic agent. Carbohydr Polym 152:1–11CrossRef Nallathambi A, Venkateshwarapuram Rengaswami GD (2016) Salt-free reactive dyeing of cotton hosiery fabrics by exhaust application of cationic agent. Carbohydr Polym 152:1–11CrossRef
Zurück zum Zitat Navarro JRG, Bergström L (2014) Labelling of N-hydroxysuccinimide-modified rhodamine B on cellulose nanofibrils by the amidation reaction. RSC Adv 4:60757–60761CrossRef Navarro JRG, Bergström L (2014) Labelling of N-hydroxysuccinimide-modified rhodamine B on cellulose nanofibrils by the amidation reaction. RSC Adv 4:60757–60761CrossRef
Zurück zum Zitat Navarro JRG, Conzatti G, Yu Y, Fall AB, Mathew R, Eden M, Bergstrom L (2015) Multicolor fluorescent labeling of cellulose nanofibrils by click chemistry. Biomacromolecules 16:1293–1300CrossRef Navarro JRG, Conzatti G, Yu Y, Fall AB, Mathew R, Eden M, Bergstrom L (2015) Multicolor fluorescent labeling of cellulose nanofibrils by click chemistry. Biomacromolecules 16:1293–1300CrossRef
Zurück zum Zitat Nechyporchuk O, Belgacem MN, Bras J (2016) Production of cellulose nanofibrils: a review of recent advances. Ind Crops Prod 93:2–25CrossRef Nechyporchuk O, Belgacem MN, Bras J (2016) Production of cellulose nanofibrils: a review of recent advances. Ind Crops Prod 93:2–25CrossRef
Zurück zum Zitat Nielsen LJ, Eyley S, Thielemans W, Aylott JW (2010) Dual fluorescent labelling of cellulose nanocrystals for pH sensing. Chem Commun 46:8929–8931CrossRef Nielsen LJ, Eyley S, Thielemans W, Aylott JW (2010) Dual fluorescent labelling of cellulose nanocrystals for pH sensing. Chem Commun 46:8929–8931CrossRef
Zurück zum Zitat Schyrr B, Pasche S, Voirin G, Weder C, Simon YC, Foster EJ (2014) Biosensors based on porous cellulose nanocrystal-poly(vinyl alcohol) scaffolds. ACS Appl Mater Interfaces 6:12674–12683CrossRef Schyrr B, Pasche S, Voirin G, Weder C, Simon YC, Foster EJ (2014) Biosensors based on porous cellulose nanocrystal-poly(vinyl alcohol) scaffolds. ACS Appl Mater Interfaces 6:12674–12683CrossRef
Zurück zum Zitat Sebe G, Ham-Pichavant F, Ibarboure E, Koffi ALC, Tingaut P (2012) Supramolecular structure characterization of cellulose II nanowhiskers produced by acid hydrolysis of cellulose I substrates. Biomacromolecules 13:570–578CrossRef Sebe G, Ham-Pichavant F, Ibarboure E, Koffi ALC, Tingaut P (2012) Supramolecular structure characterization of cellulose II nanowhiskers produced by acid hydrolysis of cellulose I substrates. Biomacromolecules 13:570–578CrossRef
Zurück zum Zitat Shen F, Xiao WX, Lin LL, Yang G, Zhang YZ, Deng SH (2013) Enzymatic saccharification coupling with polyester recovery from cotton-based waste textiles by phosphoric acid pretreatment. Bioresour Technol 130:248–255CrossRef Shen F, Xiao WX, Lin LL, Yang G, Zhang YZ, Deng SH (2013) Enzymatic saccharification coupling with polyester recovery from cotton-based waste textiles by phosphoric acid pretreatment. Bioresour Technol 130:248–255CrossRef
Zurück zum Zitat Sun XW, Lu CH, Liu Y, Zhang W, Zhang XX (2014) Melt-processed poly(vinyl alcohol) composites filled with microcrystalline cellulose from waste cotton fabrics. Carbohydr Polym 101:642–649CrossRef Sun XW, Lu CH, Liu Y, Zhang W, Zhang XX (2014) Melt-processed poly(vinyl alcohol) composites filled with microcrystalline cellulose from waste cotton fabrics. Carbohydr Polym 101:642–649CrossRef
Zurück zum Zitat Tang BT, Zhang SF, Yang JZ, Liu F (2006) Synthesis of a novel water-soluble crosslinking polymeric dye with good dyeing properties. Dyes Pigm 68:69–73CrossRef Tang BT, Zhang SF, Yang JZ, Liu F (2006) Synthesis of a novel water-soluble crosslinking polymeric dye with good dyeing properties. Dyes Pigm 68:69–73CrossRef
Zurück zum Zitat Tian WG, Zhang JM, Yu J, Wu J, Zhang J, He JS, Wang FS (2018) Phototunable full-color emission of cellulose-based dynamic fluorescent materials. Adv Funct Mater 28:1703548CrossRef Tian WG, Zhang JM, Yu J, Wu J, Zhang J, He JS, Wang FS (2018) Phototunable full-color emission of cellulose-based dynamic fluorescent materials. Adv Funct Mater 28:1703548CrossRef
Zurück zum Zitat Wang S, Lu A, Zhang LN (2016) Recent advances in regenerated cellulose materials. Prog Polym Sci 53:169–206CrossRef Wang S, Lu A, Zhang LN (2016) Recent advances in regenerated cellulose materials. Prog Polym Sci 53:169–206CrossRef
Zurück zum Zitat Wang ZH, Yao ZJ, Zhou JT, Zhang Y (2017) Reuse of waste cotton cloth for the extraction of cellulose nanocrystals. Carbohydr Polym 157:945–952CrossRef Wang ZH, Yao ZJ, Zhou JT, Zhang Y (2017) Reuse of waste cotton cloth for the extraction of cellulose nanocrystals. Carbohydr Polym 157:945–952CrossRef
Zurück zum Zitat Wu XD, Lu CH, Zhou ZH, Yuan GP, Xiong R, Zhang XX (2014) Green synthesis and formation mechanism of cellulose nanocrystal-supported gold nanoparticles with enhanced catalytic performance. Environ Sci Nano 1:71–79CrossRef Wu XD, Lu CH, Zhou ZH, Yuan GP, Xiong R, Zhang XX (2014) Green synthesis and formation mechanism of cellulose nanocrystal-supported gold nanoparticles with enhanced catalytic performance. Environ Sci Nano 1:71–79CrossRef
Zurück zum Zitat Xiong R, Zhang XX, Tian D, Zhou ZH, Lu CH (2012) Comparing microcrystalline with spherical nanocrystalline cellulose from waste cotton fabrics. Cellulose 19:1189–1198CrossRef Xiong R, Zhang XX, Tian D, Zhou ZH, Lu CH (2012) Comparing microcrystalline with spherical nanocrystalline cellulose from waste cotton fabrics. Cellulose 19:1189–1198CrossRef
Zurück zum Zitat Yue YY, Zhou CJ, French AD, Xia G, Han GP, Wang QW, Wu QL (2012) Comparative properties of cellulose nano-crystals from native and mercerized cotton fibers. Cellulose 19:1173–1187CrossRef Yue YY, Zhou CJ, French AD, Xia G, Han GP, Wang QW, Wu QL (2012) Comparative properties of cellulose nano-crystals from native and mercerized cotton fibers. Cellulose 19:1173–1187CrossRef
Zurück zum Zitat Zhang FL, Pang ZQ, Dong CH, Liu Z (2015) Preparing cationic cotton linter cellulose with high substitution degree by ultrasonic treatment. Carbohydr Polym 132:214–220CrossRef Zhang FL, Pang ZQ, Dong CH, Liu Z (2015) Preparing cationic cotton linter cellulose with high substitution degree by ultrasonic treatment. Carbohydr Polym 132:214–220CrossRef
Zurück zum Zitat Zhang YC, Jiang Y, Han L, Wang BJ, Xu H, Zhong Y, Zhang LP, Mao ZP, Sui XF (2018) Biodegradable regenerated cellulose-dispersed composites with improved properties via a pickering emulsion process. Carbohydr Polym 179:86–92CrossRef Zhang YC, Jiang Y, Han L, Wang BJ, Xu H, Zhong Y, Zhang LP, Mao ZP, Sui XF (2018) Biodegradable regenerated cellulose-dispersed composites with improved properties via a pickering emulsion process. Carbohydr Polym 179:86–92CrossRef
Metadaten
Titel
A waterborne bio-based polymer pigment: colored regenerated cellulose suspension from waste cotton fabrics
verfasst von
Lei Ding
Yang Jiang
Bijia Wang
Yingzhan Li
Zhiping Mao
Hong Xu
Yi Zhong
Linping Zhang
Xiaofeng Sui
Publikationsdatum
10.10.2018
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 12/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-018-2068-9

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